NOVELTY - Preparation of a super-hydrophobic surface composition (C1) involves electrospinning or electrospraying a mixture of a reactive group containing polymer (I), hydrocarbon/fluorinated/siloxane chemical agent (II), capped with a reactive group and a catalyst; followed by annealing and cross-linking. (I) Is formed by radical/condensation polymerization of a monomer (III) containing a reactive functional group in presence of an initiator in an inert solvent.    USE - For prevention of adhesion of dirt and foreign materials to materials, such as antennae, windows, bio-reactors, solar cells, traffic indicators public transports and animal cages; in antifouling applications in human made marine vessels and buildings, haven appliances and oil drilling platforms; in stain resistance of the materials in saunas, swimming-pools, bathrooms, kitchens, roofs, walls, facades, green-houses, garden-fences, wood appliances; and in multifunctional functional membranes, biomedical structural elements (scaffolding used in tissue engineering, wound dressing, drug delivery, artificial organs), protective shields in specialty fabrics, filter media for submicron particles in separation industry, composite reinforcement, and structures for nano-electric machines (claimed).    ADVANTAGE - Electro-spinning or spraying makes fibres/particles in the range of nanometers (one to two orders of magnitude smaller than conventional fibres), with high surface area to volume ratio. Further, the equipment retirement is simple and spinning time is much shorter than the conventional spinning. Use of electrospinning or spraying allows the formation of tunable surface properties. The coating material prepared can be tailored to various conditions over a wide range of amphipilicy (chemically and topographically), and those properties can be adjusted or tuned without adversely affected the stability, curability, or mechanical properties of the material. These materials exhibit low surface energy, low water absorptivity, stain resistance, high thermal stability, higher level of chemical inertness and excellent weatherability.