TECHNOLOGY FOCUS - INORGANIC CHEMISTRY - Preferred Components: The cationic groups are linear, cyclic and branched aliphatic, aromatic-aliphatic ammonium group and aromatic (both preferred), hydrazinium group, phosphonium group, sulfonium group, iodonium group or positively charged metal complexes. The positively charged cationic groups are anions such as F-, Cl-, Br-, I-, BF4 -, PF6 -, AsF6 -, ClO4 -, CF3SO3- (preferred), (CF3SO2)3C- or (CF3SO2)2N-. The lithium salts components are LiBF4, LiPF6, LiAsF6, LiClO4, LiCF3SO3, Li(CF3SO2)3C and/or Li(CF3SO2)2N. (I) exhibits a glass transition temperature above the room temperature. The glass transition temperature of (I) is 50-150degreesC. (I) exhibits an electric conductivity in room temperature of at least 10-4 S/cm without the addition of a plasticizer or solvent. (I) further comprises an functional additives to improve: the liability of the electrode; the passivation layer; the preparation; flame inhibiting; the separation of lithium metal on electrodes; the workability; and/or mechanical properties. The stabilizing interaction is a hydrophobic interaction, a charged-dipole interaction, a super molecular interaction or complexing.    TECHNOLOGY FOCUS - POLYMERS - Preferred Components: The group that promotes dissociation of the lithium salts is cationic groups. The polymer main chain component and the polymer compounds are polystyrene, polyacrylate, polymethacrylate, polyolefin, polyvinyl compound, polyether, poly epichlorhydrin, poly(tetrahydrofuran), polydiene, polyester, polyamide, polyimide, poly (aryletherketone), poly (arylethersulfone), poly (arylene oxide), polyarylene, polycarbonate, polyanhydride, polyurethane, polyurea, binary, tertiary, quaternary and higher, statistical and alternative copolymer, block and graft copolymer, blends form at least two of the branched polymer, hyper branched and cross linked. The polymer component is a micro-phase separated material comprises a polymer compound, where the cationic group is separated in at least one of the micro phase. The cationic groups exhibiting polymer side chains are heteroaryl compounds e.g. pyridine compound of formula (a), N+-(R3)(R2)(R4)(R5), piperidine compound e.g. of formula (b), imidazole compound of formula (c) or -Het-R1. The polymer compound is preferably poly(2-vinylpyridine), poly(4-vinylpyridine), poly(2-aminoethyl)acrylate or poly(2-aminoethyl)methacrylate. The nitrogen atoms contained in the polymer compound with linear, branched or cyclic alkyl, allyl, vinyl or partially quartneized benzyl group, where the degree of quaternizing is 5-80 (preferably 15-60)%. The cationic group exhibiting polymer main chain comprises 1-methyl-4-pyridin-4-ylmethyl-pyridine compound of formula (d) or N+(R4)(R5)-R6-N+(R4)(R5)-R7-.R1, R3-R5 = optionally substituted alkyl, branched alkyl, cycloalkyl, vinyl, allyl, benzyl, (hetero)aryl or alkaryl;R2 = optionally substituted alkyl, (hetero)aryl or alkaryl (substituted with one or more hetero atom comprising ester, ether, amide, urea, urethane, carbonate, anhydride or imide group);Het = pyridine, pyrazine, pyrazole, triazole, pyrrole, oxazoline, pyrrolidine, naphthyridine, quinoline, quinoxaline, isoquinoline or phenanthroline; andR6, R7 = substituted divalent linear, branched or cyclic alkyl, alkaryl, aryl group (substituted with allyl, vinyl or benzyl group) or heteroatoms (ester, ether, amide, urea, urethane, carbonate, anhydride or imide group). EXAMPLE - Trifluormethanesulfonic acidmethylester (75 g) was added to a mixture of poly(4-vinylpyridine) (43.7 g) and non-aqueous dimethyl formamide (350 ml) and stirred for 16 hours. To the reaction mixture dichloromethane (3 l) was added to precipitate and the solid material was separated. To the obtained product diethyl, ether extract was added. The reaction mixture was placed at 100degreesC at 10-3 mbar to give poly-(4-vinyl-N-methylpyridinium trifluormethansulfonate) (copolymer) (78 g). The obtained copolymer exhibited a glass transition temperature of 150-160degreesC and lithium bis(trifluoromethylsulfonyl)imide (5 wt.%) was added to reduce the glass transition temperature to 130-140degreesC to obtain a polymer electrolyte with ionic conductivity of 1-10-4 S/cm.