TECHNOLOGY FOCUS - ORGANIC CHEMISTRY - Preferred Compound: The phthalocyanine and oligothiophene structure containing compound is four compounds such as a compound of formula (I), preferably two compounds such as compound of formula (VI).Ar = group of formula (II);n = 1-20;andR1-R12, R,R' = H, halogen atom, 1-18C alkyl group, and one or more carbon atom in the alkyl group is optionally substituted by oxygen atom, nitrogen atom and/or sulfur atom, 1-18C alkyloxy group and one or more carbon atom in the alkyloxy group is optionally substituted by oxygen atom, nitrogen atom and/or sulfur atom, 1-18C alkyl thio group and one or more carbon atom in the alkylthio group is optionally substituted by oxygen atom, nitrogen atom and/or sulfur atom, or aromatic group.Preferred Reagent: The halogenated reagent is iodination reagent. EXAMPLE - 2,3-dicyano-3',3""-dihexyl-5,5',2',5";'2",5"';2"',5""-quinquethiophene (130 mg) and 4,5-bis(n-butoxy methyl) phthalonitrile (371 mg) were dissolved in 1-pentanol at 80degreesC under nitrogen atmosphere. Metal lithium (0.3 g) was added little by little, and stirred at 110degreesC for 16 hours. Acetone (30 ml) was added after reaction completion and stirred for 30 minutes. The precipitate was separated by filtration and acetone was washed. The filtrate was concentrated, acetic acid (20 ml) was added and stirred for 1 hour, and hexakis (butoxymethyl) tribenzo(d,i,n)-5-(3,3"-dihexyl-2,2';5',2";5",2"'-quarter thiophene-5-yl)thiopheno(2,3-s)porphyrazine of formula (VI) was filtered as precipitate. The filtrate was concentrated under reduced pressure. Water (100 ml) was added and extracted with methylene chloride (80 mlx3). The extract was washed with water (200 ml), dried and concentrated under reduced pressure. The crude product (VI) was obtained. The product was purified by column chromatography and product (VI) (99 mg) was obtained. The product had melting point of 133-141degreesC. The product was used as organic semiconductor electronic material for optoelectric optoelectronic components.