TECHNOLOGY FOCUS - INORGANIC CHEMISTRY - Preferred Component: The acid catalyst comprises acidic alumina, aluminum phosphate, silica-alumina phosphate, amorphous silica-alumina, aluminosilicate, zirconia, zirconia sulfate, tungstated zirconia, tungsten carbide, molybdenum carbide, titania, carbon sulfate, carbon phosphate, silica phosphate, acidic resin, heteropolyacid and/or inorganic acid; modifier comprising cerium (Ce), yttrium (Y), scandium (Sc), lanthanum (La), lithium (Li), sodium (Na), potassium (K), rubidium (Rb), cesium (Cs), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), phosphorus (P), boron (B), bismuth (Bi), gallium (Ga), indium (In), zinc (Zn), iron (Fe), molybdenum (Mo), silver (Ag), gold (Au), nickel (Ni), tantalum (Ta) and/or lanthanide; oxide of titanium (Ti), zirconium (Zr), vanadium (V), niobium (Nb), Ta, Mo, chromium (Cr), tungsten (W), manganese (Mn), rhenium (Re), aluminum (Al), Ga, In, Fe, cobalt (Co), iridium (Ir), Ni, silicon (Si), copper (Cu), Zn, tin (Sn), cadmium (Cd) and/or P; metal comprising Cu, Ag, Au, platinum (Pt), Ni, Fe, Co, ruthenium (Ru), Zn, Cd, Ga, In, rhodium (Rh), palladium (Pd), Ir, Re, Mn, chromium (Cr), Mo, W, tin (Sn), osmium (Os), and/or their alloys; and bifunctional pentasil ring-containing aluminosilicate zeolite. The deoxygenation catalyst comprises a support, and Re, Cu, Fe, Ru, Ir, Co, Rh, Pt, Pd, Ni, W, Os, Mo, Ag, Au, Cr, V, Nb, Mn, Ta, Ti, Zr, Y, La, Sc, Zn, Cd, Sn, germanium (Ge), P, Al, Ga, In, thallium (Tl) and/or their alloys. The aqueous phase reforming catalyst comprises a support, and Fe, Ru, Os, Ir, Co, rhodium (Rh), Pt, Pd, Ni, Cu, B, Mn, Re, Cr, Mo, Bi, W, V, Nb, Ta, Ti, Zr, Y, La, Sc, Zn, Cd, Ag, Au, Sn, Ge, P, Al, Ga, In, Tl and/or their alloys; and Ni alloyed or mixed with Sn, Ge, Bi, B, Cu, Re, Ru, Fe, and/or their alloys. The reforming and deoxygenation catalyst comprise Pt alloyed or mixed with Ni, Ru, Cu, Fe, Rh, Re, and/or alloys; and Ru alloyed or mixed with Ge, Bi, B, Ni, Sn, Cu, Fe, Rh, Pt and/or alloys. The hydrogenation catalyst comprises a support, a phosphate, and Cr, Mo, W, Re, Mn, Cu, Cd, Fe, Ru, Os, Ir, Co, Rh, Pt, Pd, Ni, Au, Ag, Zn, Sn, Bi, B, Cr, Mn, oxygen, P and/or their alloys; and alkaline earth metal oxide. The aqueous phase reforming catalyst, deoxygenation catalyst and acid catalyst are atomically identical. The support comprises nitride, carbon, silica, alumina, zirconia, titania, vanadia, ceria, boron nitride, heteropolyacid, kieselguhr, hydroxyapatite, zinc oxide, and/or chromia (preferably hydrogen peroxide treated carbon).    TECHNOLOGY FOCUS - ORGANIC CHEMISTRY - Preferred Components: The H2 comprises generated H2, external H2 and/or recycled H2. The supplemental H2 comprises external H2 and/or recycled H2. The oxygenated hydrocarbon comprises C1-12O1-11 (preferably C1-6O1-6) hydrocarbon comprising polysaccharides, disaccharides, monosaccharides, cellulose derivatives, lignin derivatives, hemicellulose, alditol, sugar, sugar alcohol, glucose, fructose, sucrose, maltose, lactose, mannose, xylose, arabitol, erythritol, glycerol, isomalt, lactitol, malitol, mannitol, sorbitol and/or xylitol. The oxygenate comprises methanol, ethanol, n-propyl alcohol, isopropyl alcohol, butyl alcohol, pentanol, hexanol, cyclopentanol, cyclohexanol, 2-methylcyclopentanol, hydroxyketones, cyclic ketones, acetone, propanone, butanone, pentanone, hexanone, 2-methyl-cyclopentanone, ethylene glycol, 1,3-propanediol, propylene glycol, butanediol, pentanediol, hexanediol, methylglyoxal, butanedione, pentanedione, diketohexane, hydroxyaldehyde, acetaldehyde, propionaldehyde, butyraldehyde, pentanal, hexanal, formic acid, acetic acid, propionic acid, butanoic acid, pentanoic acid, hexanoic acid, lactic acid, furan, tetrahydrofuran, dihydrofuran, 2-furan methanol, 2-methyl-tetrahydrofuran, 2,5-dimethyltetrahydrofuran, 2-ethyl-tetrahydrofuran, 2-methylfuran, 2,5-dimethylfuran, 2-ethylfuran, hydroxylmethylfurfural, 3-hydroxytetrahydrofuran, tetrahydro-3-furanol, 5-hydroxymethyl-2(5H)-furanone, dihydro-5-(hydroxymethyl)-2(3H)-furanone, tetrahydro-2-furoic acid, dihydro-5-(hydroxymethyl)-2(3H)-furanone, tetrahydrofurfuryl alcohol, 1-(2-furyl)ethanol, and hydroxymethyltetrahydrofurfural, and/or their isomers. The greater than or equal to 4C alkane comprises 4-30C alkane comprising 4-9C, 7-14C and/or 12-24C. The greater than or equal to 4C alkene comprises 4-30C alkene consisting of 4-9C, 7-14C and/or 12-24C alkene. The cycloalkane comprises mono-substituted branched greater than or equal to 3C alkyl(ene), straight chain greater than or equal to 1C alkyl(ene) and/or phenyl; or multi-substituted greater than or equal to 5C cycloalkane. The substituted group (preferably greater than or equal to 5C cycloalkane) is substituted with branched 3-12C alkyl(ene), straight chain 1-12C alkyl(ene), and/or phenyl. The greater than or equal to 5C cycloalkene comprises a mono- or multi-substituted greater than or equal to 5C cycloalkene. The fused aryl is optionally substituted by branched greater than or equal to 3C and straight chain greater than or equal to 2C alkyl(ene), straight chain greater than or equal to 1C alkyl and/or phenyl. The composition comprises benzene, toluene, xylene, ethyl benzene, para-xylene, meta-xylene, ortho-xylene, 9C aromatics, and/or their isomers. The greater than or equal to 4C alcohol comprises compound of formula R1-OH. The greater than or equal to 4C ketone comprises a compound of formula R3-C(=O)-R4.R1= greater than or equal to 4C alkyl, straight chain greater than or equal to 4C alkyl(ene), branched greater than or equal to 4C alkylene, optionally substituted greater than or equal to 5C cycloalkane, optionally substituted greater than or equal to 5C cycloalkene, aryl and/or Ph; andR3, R4=branched greater than or equal to 3C alkyl(ene), straight chain greater than or equal to 1C alkyl, straight chain greater than or equal to 2C alkylene, optionally substituted greater than or equal to 5C cycloalkene and/or Ph.Preferred Composition: The molar ratio of total oxygen atoms in oxygenated hydrocarbons to total hydrogen atoms in external H2 is less than 1:1. Preferred Method: The H2 is generated at 100-450 (preferably 200-280) degrees C and 72-1300 (preferably 200-725) psig. The support is modified by treating with modifier consisting of silanes, alkali compounds, alkali earth compounds and/or lanthanides; and carbon nanotubes, carbon fullerenes or zeolites. The method further comprises dewatering the reaction stream prior to reacting oxygenate with acid catalyst, reacting in liquid and/or vapor phase a sugar, sugar alcohol or polyhydric alcohol, furfural, carboxylic acid, ketone, or furan with supplemental H2 in presence of hydrogenation catalyst at 80-300 (preferably 110-250) degrees C and 100-2400 (preferably 100-2000) psig, catalytically reacting portion of oxygenated hydrocarbon with supplemental H2 in presence of deoxygenation catalyst to produce oxygenate, and catalytically reacting greater than or equal to 4C compound with finishing catalyst comprising a support, Cu, Ni, Fe, Co, Ru, Pd, Rh, Pt, Ir, Os and/or their alloys; and modifier consisting of Au, Ag, Cr, Zn, Mn, Sn, Cu, Cr, Bi and/or their alloys. The catalytic reaction of oxygenated hydrocarbon is conducted with external H2. Preferred Conditions: The reforming step is at 100-450 (preferably 100-300) degrees C, and pressure where the water and oxygenated hydrocarbon are gaseous (preferably 72-1300 psig); or at 80-400 degrees C, and reforming pressure where the water and oxygenated hydrocarbon are liquid. The deoxygenation is at 100-600 (preferably 200-280) degrees C and pressure where the water and oxygenated hydrocarbon are gaseous (preferably greater than or equal to 0.1 atm). The condensation is at 80-500 degrees C and greater than or equal to 0.1 atm. EXAMPLE - A bimetallic catalyst system containing platinum (Pt) and rhenium (Re) (5 wt.% Pt with a molar ratio of Pt:Re of 1:2.5) supported on Calgon UU(RTM: activated carbon) was prepared using incipient wetness techniques. Activated carbon was added slowly to a 30% hydrogen peroxide solution. After addition of carbon was completed, the mixture was left overnight. The aqueous phase was decanted and the carbon was washed three times with deionized water, and then dried under vacuum at 100 degrees C. An aqueous solution, with a volume equal to incipient wetness volume for the carbon to be impregnated, 10.4 mL, and containing dihydrogen hexachloroplatinate (IV) hexahydrate (39.85% Pt) and perrhemic acid (HReO4) solution (76.41% HReO4) was applied dropwise, while stirring, to hydrogen peroxide functionalized carbon. The wetted carbon was dried at 100 degrees C under vacuum.