TECHNOLOGY FOCUS - INORGANIC CHEMISTRY - Preferred compound: The catalyst comprises elements from the group: Cu-Zn-Fe-K-Al or Fe:Cu:Zn:Al:Pd:Ga. The catalyst has at least three components and those components constitute 0.1-50% of the catalyst. Preferred Properties: The carbon dioxide has a concentration of 300-500000 ppm, preferably, 377-500000 ppm. The catalyst component constitutes 0.01-4 weight ratio in the catalyst.    TECHNOLOGY FOCUS - ORGANIC CHEMISTRY - Preferred Process: The hydrogen is produced from a combustion free source of energy, and electrolysis of water. The source of energy is solar power. The carbon dioxide is concentrated to essentially pure carbon dioxide with only trace amounts of other components using separation elements such as membrane methods, pressure swing equipment methods, distillation methods, and/or hindered amine capture methods. The separation process produces recycled carbon dioxide. separation method is distillation. The combustible compounds and other saleable organic compounds products are essentially stripped from unreacted reactants in the reactor effluent and the ethanol and other saleable organic compounds product are separated, stored and distributed. The hydrogen and carbon monoxide are obtained from one of the addition of the processes of partial reaction of natural gas, as the Boudouard reactor, and/or electrolysis of water. Preferred Components: The catalytic reactor system has multiple reactors and reactant recycle. The combustible ethanol and other saleable organic compounds products are sequestered in long term storage. The long term storage is depleted oil, salt, stone caverns or gas wells. Preferred Compounds: The ethanol and methanol with measurable minor component of other organic compounds comprises at least half of product combustible saleable organic compounds. The combustible saleable organic compound is acetic acid. Preferred Properties: The combustible compounds and other saleable organic compounds are produced with up to 20 carbon atoms per molecule.