TECHNOLOGY FOCUS - INORGANIC CHEMISTRY - Preferred Material: The alkali metal ion containing substance is lithium trifluoromethane sulfonate (LiSO3CF3), LiCOOC2F5, LiN(SO2CF3)2, LiC(SO2CF3)3, lithium perchlorate (LiClO4), lithium hexafluoroarsenide (LiAsF6), lithium tetrafluoroboride (LiBF4), lithium hexafluorophosphide (LiPF6), lithium hexafluoroantimonide (LiSbF6), lithium iodide (LiI), lithium bromide (LiBr), and/or lithium chloride (LiCl). The transition metal oxides are lithium vanadium oxide (Li2.5V6O13), Li1.2V2O5, lithium cobalt oxide (LiCoO2), lithium nickel oxide (LiNiO2), lithium manganese oxide (LiMn2O4), LiMnO2, or LiNi1-xMxO2.M=Co, Mg, Al, or Ti.The transition metal chalcogenides are lithium niobium selenide (LiNbSe3), lithium titanium sulfide (LiTiS2), or lithium molybdenum sulfide (LiMoS2).    TECHNOLOGY FOCUS - METALLURGY - Preferred Material: The anode is made of a material that consists of lithium, lithium alloys, lithium-carbon intercalation compounds, lithium-graphite intercalation compounds, lithium metal oxide intercalation compounds, and/or lithium metal sulfide intercalation compounds, or their mixtures and alkali metals.    TECHNOLOGY FOCUS - ORGANIC CHEMISTRY - Preferred Compound: The nonaqueous solvent is ethylene carbonate, dimethyl carbonate, diethyl carbonate, propylene carbonate, ether, organic carbonate, lactone, formate, ester, sulfonate, nitrite, oxazolidinone, tetrahydrofuran, 2-methyltetrahydrofuran, 4-methyl-1,3-dioxolane, 1,3-dioxolane, 1,2-dimethoxyethane, dimethoxymethane, gamma-butyrolactone, methyl formate, sulforane, acetonitrile, 3-methyl-2-oxazolidinone, and/or N-methyl-2-pyrrolidinone. The curing initiator is a photocuring initiator and/or a heat-curing initiator. The photocuring initiator is dimethoxyphenyl acetophenone (DMPA), t-butylperoxypivalate, ethyl benzoin ether, isopropyl benzoin ether, alpha-methyl benzoin ethyl ether, benzoin phenyl ether, alpha-acyloxime ester, alpha,alpha-diethoxyacetophenone, 1,1-dichloroacetophenone, 2-hydroxy-2-methyl-1-phenylpropane-1-on, 1-hydroxycyclohexyl phenyl ketone, anthraquinone, thioxanthone, isopropyl thioxanthone, chlorothioxanthone, benzophenone, p-chlorobenzophenone, benzyl benzoate, benzoyl benzoate, and/or Michler's ketone; and the heat-curing initiator is azoisobutyronitrile compounds and/or peroxide compounds.    TECHNOLOGY FOCUS - POLYMERS - Preparation (Disclosed): (1) Is synthesized by hydrosilylating a polymethylcyclo polysiloxane with allyl trifluoro sulfonamide, polyalkylene glycol allyl ether, allyl cyanide, and allyl propylene carbonate to synthesize the siloxane-containing monomer, and reacting the monomer with a polymerization terminator using a fuming sulfuric acid as catalyst.Preferred Component: The gel polymer electrolyte comprises a nonaqueous solvent, an anion receptor, a curing initiator, and an alkali metal ion containing substance. The solid polymer electrolyte comprises a plasticizer, a curing initiator, and an alkali metal ion containing substance. It comprises the substance consisting an anion receptor, polyalkyleneglycol dialkylether, and/or nonaqueous solvent, as plasticizer. The organic disulfide redox polymers are prepared by reversible electrochemical dimerization/division or polymerization/dissociation.Preferred Compound: The anion receptor is from linear or cyclic siloxane compounds having amine substituted with electron withdrawing groups, or at least one of polyalkylene oxide group, cyano group, and propylene carbonate group as a side branch in addition to the amine substituted with electron withdrawing groups; linear hydrocarbon compounds having amine substituted with electron withdrawing groups at its terminal group; or aromatic hydrocarbon compounds having amine substituted with electron withdrawing groups. The polyalkyleneglycol dialkylether is polyethyleneglycol dimethylether (PEGDME), polyethyleneglycol diethylether, polyethyleneglycol dipropylether, polyethyleneglycol dibutylether, polyethyleneglycol diglycidylether, polypropyleneglycol dimethylether, polypropyleneglycol diglycidylether, polypropyleneglycol/polyethyleneglycol copolymer terminated with dibutylether, or polyethyleneglycol/polypropyleneglycol/polyethyleneglycol block copolymer terminated with dibutylether. The cathode is made of a material that consists of transition metal oxides, transition metal chalcogenides, poly(carbondisulfide)polymers, organic disulfide redox polymers, polyaniline, organic disulfide/polyaniline complexes, or their mixtures and oxychlorides. The organic disulfide/polyaniline complexes are mixtures of polyaniline and 2,5-dimercapto-1,3,4-thiadiazole.Preferred Composition: The polymer electrolyte comprises (pbw): crosslinker (1-40), nonaqueous solvent (0.5-86.5), anion receptor (0-30), alkali metal ion containing substance (3- 60), and curing initiator (0.5-5). It comprises (pbw): crosslinker (10-95), substance (0.5-86.5) consisting anion receptor, polyalkyleneglycol dialkylether, and/or nonaqueous solvent, alkali metal ion containing substance (3-60), and curing initiator (0.5-5). EXAMPLE - Compound of formula (A) (0.61 g), compound of formula (B) (5.00 g), and 1,1,3,3-tetramethyldisiloxane (D2)-1,3-di(propoxy-6,7-propane diacrylate) (1.16 g) were mixed, and added with fuming sulfuric acid (H2SO4) (0.03 ml) dropwise, and the mixture stirred for 6 hours at 30-35degreesC. Distilled water (0.03 ml) was added and stirred for 1 hour. The reaction products were added to chloroform (50 ml) and saturated aqueous sodium sulfate (Na2SO4) solution (30 ml), and neutralized and washed with 5 wt.% of sodium carbonate (Na2CO3) aqueous solution until neutrality was reached. Magnesium sulfate (MgSO4) was added to the neutralized reactants and the mixture was stirred. The precipitates were filtered, hydroquinone (100 ppm) as a polymerization inhibitor was added, and the resultant was evaporated under the reduced pressure to obtain the crosslinker.