NOVELTY - Substituted anthracene compounds (I) as an organic electroluminescent material, are new.    USE - (I) are useful as an organic electroluminescent material, which is useful to prepare an organic electroluminescent device, a white electroluminescent device, and an organic solar cell (all claimed).    ADVANTAGE - (I) have good luminous efficiency, excellent color purity and excellent operation life property while using in organic light emitting device.    DETAILED DESCRIPTION - Substituted anthracene compounds of formula (I) as an organic electroluminescent material, are new.    either R1-R8, R9-R12, R13, R14 - R26, R31-R43, R51-R65 = H, halo, (1-60C)alkyl, (6-60C)aryl, (3-60C)heteroaryl, 5- or 6-membered heterocycloalkyl containing heteroatom(s) of N, O or S, (3-60C)cycloalkyl, tri(1-60C)alkylsilyl, di(1-60C)alkyl(6-60C)arylsilyl, tri(6-60C)arylsilyl, adamantyl, (7-60C)bicycloalkyl, (2-60C)alkenyl, (2-60C)alkynyl, (1-60C)alkoxy, CN, (1-60C)alkylamino, (6-60C)arylamino, (6-60C)ar(1-60C)alkyl, (6-60C)aryloxy, (6-60C)arylthio, (1-60C)alkoxycarbonyl, carboxyl, NO2 or OH; or    R1-R8, R9-R12, R14 and R15, R17 and R18, R22 and R23, R24 and R25, R31-R43, R51 and R52, R54 and R55, R59 and R60, R61 and R62, R64 and R65 may be linked to an adjacent substituent via (3-60C)alkylene or (3-60C)alkenylene = alicyclic ring or mono- or poly- cyclic aromatic ring, provided that R1-R8 cannot be H all at the same time;    L1 = chemical bond, (6-60C)arylene or (3-60C)heteroarylene, where the (hetero)arylene may be further substituted with (1-60C)alkyl, halo, CN, (3-60C)cycloalkyl, tri(1-60C)alkylsilyl, di(1-60C)alkyl(6-60C)arylsilyl, tri(6-60C)arylsilyl, adamantyl, (7-60C)bicycloalkyl, (2-60C)alkenyl, (2-60C)alkynyl, (1-60C)alkoxy, CN, (1-60C)alkylamino, (6-60C)arylamino, (6-60C)ar(1-60C)alkyl, (6-60C)aryloxy, (6-60C)arylthio, (1-60C)alkoxycarbonyl, carboxyl, NO2 or OH, where the alkyl, (hetero)aryl, (hetero)cycloalkyl, trialkylsilyl, dialkylarylsilyl, triarylsilyl, adamantyl, bicycloalkyl, alkenyl, alkynyl, alkylamino or arylamino of Ar1, R1-R26, R31-R43 and R51-R63 may be further substituted by R13 (except H);    Ar1 = R13 (except the groups H and halo), or a substituent of (hetero)aryl compounds of formulae (aa-cc);    W1, X = chemical bond, -C(R14)(R15)-, -N(R16)-, -S-, -O-, -Si(R17)(R18)-, -P(R19)-,-C(=O)-,- B(R20)-, -In(R21)-, -Se-, -Ge(R22)(R23)-, -Sn(R24)(R25)- or -Ga(R26)-;    Y1, Z = chemical bond, -(CR51R52)C-, -N(R53)-, -S-, -O-, -Si(R54)(R55)-, -P(R56)-, -C(=O)-, -B(R57)-, -In(R58)-, -Se-, -Ge(R59)(R60)-, -Sn(R61)(R62)-, Ga(R63)- or -(R64)C=C(R65)-;    a = 0-3; and    b, c = 1-4.    INDEPENDENT CLAIMS are included for:    (1) an organic electroluminescent device comprising a first electrode, a second electrode and at least one organic layer(s) interposed between the first and second electrode, where the organic layer comprising (I) and/or dopant(s) comprising amine compounds of formula (R121-N(R122)-L11-N(R123R124)) or 9-benzothiazol-2-yl-1,1,6,6-tetramethyl-2,3,5,6,8,9-hexahydro-1H,4H-11-oxa-3a-aza-benzo(de)anthracen-10-one;    (2) a white electroluminescent device comprising (I); and    (3) an organic solar cell comprising (I).    L11 = (6-60C)arylene with or without at least one substituent of R13 (except H and (3-60C) alkyl) or (4-60C) alkyl, where the alkyl, (hetero)aryl, (hetero)cycloalkyl, trialkylsilyl, dialkylarylsilyl, triarylsilyl, adamantyl, bicycloalkyl, alkenyl, alkynyl, alkylamino or arylamino substituent on the arylene may be further substituted by R13 (except H and (3-60C) alkyl); and either    R121-R124 = (1-60C)alkyl, (6-60C)aryl, (4-60C)heteroaryl, (6-60C)arylamino, (1-60C)alkylamino, 5- or 6-membered heterocycloalkyl containing heteroatoms of N, O or S, or (3-60C)cycloalkyl; or    R121-R124 may be linked to an adjacent substituent via (3-60C)alkylene or (3-60C)alkenylene with or without a fused ring = alicyclic ring, mono- or poly- cyclic ring.