TECHNOLOGY FOCUS - ORGANIC CHEMISTRY - Preparation (claimed): A perfluoroalkyl (meth)acrylate, and mercapto group-containing alkoxy silane or amino group-containing alkoxy silane, (meth)acrylic acid polyfluoroalkyl ester, and mercapto group-containing alcohol, mercapto group-containing phenol, amino group-containing alcohol, amino group-containing phenol or mercapto group-containing amine, or halo polyfluoroalkyl, and mercapto group-containing alcohol, mercapto group-containing phenol, amino group-containing alcohol, amino group-containing phenol or mercapto group-containing amine, or halo polyfluoroalkyl, and thiolation agent or aminating agent, are reacted to form polyfluoroalkyl alcohol, polyfluoroalkyl phenol, polyfluoroalkyl amine or polyfluorothiol respectively. The obtained compound is reacted with isocyanato group-containing (meth)acrylate or isocyanato group-containing alkoxysilane, chloromethyl group-containing (meth)acrylate, chloromethyl group-containing styryl group or chloromethyl group-containing alkoxysilane to form polymerizable carbonyl compound. Or, the polyfluoroalkyl alcohol, polyfluoroalkyl phenol, polyfluoroalkyl amine or polyfluorothiol, is reacted with (meth)acrylic acid, (meth)acrylic acid halide or (meth)acrylic acid anhydride to form polymerizable carbonyl compound. Or, the polyfluoroalkyl alkanol, polyfluoroalkyl amine or polyfluorothiol, is reacted with isocyanato group-containing alkoxysilane or isocyanato group-containing (meth)acrylate to form polymerizable carbonyl compound. Or, the polyfluoroalkyl ester (meth)acrylate, is reacted with trialkoxysilane or trihalo silane to form polymerizable carbonyl compound. Preferred Compound: Alternately, the polymerizable carbonyl compound of formulae: (Rf-R1-O(CO)-R5-)mX-R6-Si(R7)n(-Y')3-n or Rf-R4-OCONH-R6-Si(R7)n(-Y')3-n.R4,R6=1-4C alkylene or 6-10C arylene;R5=ethylene or 1-methyl ethylene;R7=methyl;X=-O-, -S-, -N(-asterisk)- or -NH-;Y'=1-3C alkoxy, hydroxyl or halo;n=0 or 1;andm=1 or 2.Preferred Material: A surfactant comprises the polymerizable carbonyl compound and a polymeric compound. The surfactant is a solution, emulsion or aerosol. Preferred Component: The surfactant is processed in to-be-processed component to obtain surface treated component. EXAMPLE - 2-(Perfluorooctyl)ethyl acrylate (in weight parts) (12.5), 3-(trimethoxysilyl)propane-1-thiol (4.73) and 2,2'-azobisisobutyrinitrile (198x 10-3), were dissolved in ethyl methyl ketone (155), and refluxed for 17 hours under argon atmosphere to obtain 2-(perfluorooctyl)ethyl (3-((3-trimethoxysilyl)propyl)thiopropionate).