NOVELTY - Composition (I) comprises: either 2,3,3,3-tetrafluoropropene (HFO-1234yf) and at least one additional compound comprising e.g. E- or Z-1,3,3,3-tetrafluoropropene, 1,1,1,2-tetrafluoropropane or 1,1,1,3-tetrafluoropropane (HFC-254fb); or 1,1,1,2,3-pentafluoropropane (HFC-245eb) and at least one additional compound comprising e.g. E- or Z-1,3,3,3-tetrafluoropropene (HFO-1234ze), 1,1,1,3,3-pentafluoropropane (HFC-245fa) or 1,1,1,2,2,3-hexafluoropropane (HFC-236cb).    USE - (I) is useful as: heat transfer compositions for refrigeration, air-conditioning and heat pump systems; aerosol propellants, foaming agents, blowing agents, solvents, cleaning agents, carrier fluids, displacement drying agents, buffing abrasion agents, polymerization media, expansion agents for polyolefins and polyurethane, gaseous dielectrics, extinguishing agents, and fire suppression agents in liquid or gaseous form; and as a working fluid used to carry heat from a heat source to a heat sink. (I) is useful in e.g.: heat transfer systems including air conditioners, freezers, refrigerators, heat pumps, water chillers, flooded evaporator chillers, direct expansion chillers, centrifugal chillers, walk-in coolers, heat pumps, mobile refrigerators and mobile air conditioning units; mobile refrigeration apparatus, mobile air conditioning or mobile heating apparatus, which is any refrigeration, heating apparatus incorporated into a transportation unit for the road, rail, sea or air; and stationary heat transfer systems including e.g. stationary air conditioning and heat pumps (including chillers (including centrifugal chillers), high temperature heat pumps, residential, commercial or industrial air conditioning systems and including window, ductless, ducted, packaged terminal, and those exterior but connected to the building such as rooftop systems).    ADVANTAGE - (I) has low global warming potential compounds.    DETAILED DESCRIPTION - Composition (I) comprises: either 2,3,3,3-tetrafluoropropene (HFO-1234yf) and at least one additional compound comprising E- or Z-1,3,3,3-tetrafluoropropene (HFO-1234ze), 1,1,1,2-tetrafluoropropane (HFC-254eb), 1,1,1,3-tetrafluoropropane (HFC-254fb), 1,1,1-trifluoropropene (HFO-1243zf), 1,1,1,2,3-pentafluoropropane (HFC-245eb), 1,1,1,3,3-pentafluoropropane (HFC-245fa), 1,1,1,2,2-pentafluoropropane (HFC-245cb), 1,1,1,2,2,3-hexafluoropropane (HFC-236cb), 1,1,1,2,3,3-hexafluoropropane (HFC-236ea), 1,1,1,3,3,3-hexafluoropropane (HFC-236fa), 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea), 1,1,1,2,2,3,3-heptafluoropropane (HFC-227ca), 1,1,2,3,3-pentafluoropropene (HFO-1225yc), 1,1,1,3,3-pentafluoropropene (HFO-1225zc), 1,2,3,3,3-pentafluoropropene (HFO-1225ye), 3,3,3-trifluoropropyne, methane, ethane, propane, trifluoromethane (HFC-23), 1,1,1-trifluoroethane (HFC-143a), 1,1,2,2-tetrafluoroethane (HFC-134), 1,1,1,2-tetrafluoroethane (HFC-134a), 1,1-difluoroethene (HFO-1132a) or hexafluoropropene (FC-1216); or HFC-245eb and at least one additional compound comprising HFO-1234ze, HFC-245fa, HFC-236cb, HFC-236ea, HFC-236fa, HFC-227ea, HFC-227ca, HFO-1225yc, HFO-1225zc, HFO-1225ye, methane, ethane, propane, HFC-23, HFC-143a, HFC-134, HFC-134a, FC-1216, HFO-1234yf, HFC-254eb, HFO-1243zf, or HFC-254fb.