TECHNOLOGY FOCUS - INORGANIC CHEMISTRY - Preferred Components: The solution further comprises: an inorganic precursor to convert hydrophilic domains formed by the third block repeat unit to organic/inorganic hybrid hydrophilic domains containing a corresponding inorganic material; and an inorganic precursor to convert the hydrophilic domain formed by the hydrophilic second block repeat unit to an organic/inorganic hybrid hydrophilic domain containing a corresponding inorganic material.    TECHNOLOGY FOCUS - POLYMERS - Preferred Composition: (I) further comprises a hydrophobic protective layer on the barrier layer, where the hydrophobic protective layer contains a block copolymer having a hydrophobic first block repeat unit and a second hydrophilic block repeat unit. In (I), each of the first, second and third block repeat units has a weight average molecular weight of 1000-200000 grams per mole and a polydispersity index (weight average molecular weight (Mw)/number average molecular weight (Mn)) of 1-1.3. In (I), each of the hydrophobic first block repeat unit and the hydrophilic second block repeat unit has a weight average molecular weight of 1000-200000 grams per mole and a Mw/Mn of 1-1.3 Preferred Components: The barrier layer is inorganic layers, organic/inorganic hybrid layers, or laminates of organic layers and inorganic layers. The third block repeat unit has a contact angle with water of 60 degrees or less and a surface energy of at least about 35 millinewtons per meter. Preferred Method: The soft block repeat unit forms a soft block domain inside the adhesive layer and the third block repeat unit forms hydrophilic domains on both surfaces of the soft block domain. The soft block repeat unit forms a soft block domain, the third block repeat unit forms hydrophilic domains, and the soft block domain and the hydrophilic domains are arranged alternatively. The soft block repeat unit forms a soft block domain, the third block repeat unit forms hydrophilic domains, and the barrier layer is in contact with one of the hydrophilic domains. The soft block repeat unit forms a soft block domain, the third block repeat unit forms hydrophilic domains, and the hydrophilic domains further contain an inorganic material. The hydrophobic first block repeat unit forms a hydrophobic domain and the hydrophilic second block repeat unit forms a hydrophilic domain in contact with the barrier layer. The hydrophobic first block repeat unit forms a hydrophobic domain, the hydrophilic second block repeat unit forms a hydrophilic domain, and the hydrophilic domain further contains an inorganic material. The method further comprises applying a solution of the block copolymer having the hydrophobic first block repeat unit and the hydrophilic second block repeat unit in a solvent to the barrier layer to form the hydrophobic protective layer.