NOVELTY - Yttria stabilized zirconia (YSZ) electrolyte pulp material is printed on upper surface of anode support using silk screen and dried to form anode support printed with YSZ electrolyte film. The printed support is sintered and YSZ and samarium doped ceria (SDC) electrolyte pulp material is printed on sintered support and dried to obtain anode support with transition layer. The anode support is sintered, and SDC pulp material is printed on support, dried and sintered to obtain anode support electrolyte composite film.    USE - Manufacture of anode support electrolyte composite film for battery.    ADVANTAGE - The anode support electrolyte composite film is manufactured at high yield without breakage, and provides battery with favorable open circuit voltage characteristics.    DETAILED DESCRIPTION - Mixture of nickel oxide powder, yttria stabilized zirconia (YSZ) powder, starch and absolute ethyl alcohol in ratio of 5:5:2:3 is added into a planet type ball mill whose grinding ball is agate ball, ground for 2-12 hours at rotating speed of 100-300 rpm in material ratio of 2.5:1, and dried at 60-300 degrees C for 2-10 hours. The dried mixture is made into anode sheet having thickness of 0.3-1 mm and diameter of 0.5-1.5 cm under pressure of 200-360 MPa and anode sheet is sintered at 900-1200 degrees C for 1-6 hours to obtain anode support. YSZ powder having average grain diameter of 0.05-1.2 mm is put into planet type ball mill whose grinding ball is agate ball, and ground for 2-10 hours at material ratio of 2.5:1. The ground YSZ powder and organic cementing agent are mixed and ground in weight ratio of 4:5 in an agate grinding bowl for 30 minutes to obtain YSZ electrolyte pulp material. Samarium-doped ceria (SDC) powder having average grain diameter of 0.02-1 mm is put into planet type ball mill whose grinding ball is agate ball, and ground for 2-10 hours in material ratio of 2.5:1. The ground powder and organic cementing agent are mixed and ground in weight ratio of 4:5 in an agate grinding bowl for 30 minutes to obtain SDC electrolyte pulp material. The YSZ electrolyte pulp material and the SDC electrolyte pulp material are mixed and ground in weight ratio of 1:1 to obtain YSZ and SDC electrolyte pulp material. The YSZ electrolyte pulp material is printed on upper surface of anode support using silk screen having pore diameter of 400-500 meshes and dried repeatedly for 0.5-10 minutes at 70-200 degrees C until upper surface of anode support is formed with 2-6 mm thick YSZ electrolyte film. Anode support printed with YSZ electrolyte film is obtained. The anode support printed with YSZ electrolyte film is put into a high temperature case-shaped resistor furnace, temperature is raised to 300-500 degrees C for 0.2-3 hours, 501-900 degrees C for 0.3-5 hours and 901-1104 degrees C for 0.5-3 hours, and cooled to room temperature, to obtain sintered anode support with YSZ electrolyte film. The YSZ and SDC electrolyte pulp material is printed on surface of sintered anode support with YSZ electrolyte film via silk screen having pore diameter of 400-500 meshes and dried repeatedly for 0.5-10 minutes at 70-200 degrees C until surface of YSZ electrolyte film is formed with 2-4 mm thick YSZ and SDC transition layer. Anode support printed with YSZ and SDC transition layer is formed. The anode support printed with YSZ and SDC transition layer is put into a high temperature case-shaped resistor furnace, temperature is raised to 300-500 degrees C for 0.2-3 hours and 501-1000 degrees C for 0.3-5 hours, temperature is retained for 1-3 hours at 501-1000 degrees C, temperature is reduced to 500-999 degrees C for 0.5-3 hours and finally cooled to room temperature. Sintered anode support with YSZ and SDC transition layer is obtained. The SDC electrolyte pulp material is printed on surface of sintered anode support with YSZ and SDC transition layer using silk screen having pore diameter of 400-600 meshes and dried repeatedly for 0.5-10 minutes at 70-200 degrees C until surface of YSZ and SDC transition layer is formed with a 6-14 mm thick SDC electrolyte film to obtain anode support printed with SDC electrolyte film. The anode support printed with SDC electrolyte film is put into a muffle, temperature is raised to 300-500 degrees C for 0.2-3 hours, 501-1000 degrees C for 0.3-5 hours and 1001-1405 degrees C for 0.5-2 hours, and temperature is retained for 1-6 hours at 1001-1405 degrees C. The temperature is reduced to 900-1104 degrees C for 0.5-3 hours, temperature of muffle is reduced to 500-900 degrees C for 0.3-5 hours, and finally cooled to room temperature, to obtain anode support electrolyte composite film.