TECHNOLOGY FOCUS - ORGANIC CHEMISTRY - Preferred Film: The added functionality of the SOF arises from an inclined property of the segments of the SOF. The added functionality of the SOF does not arise from the inclined property of the segments of the SOF. The SOF is formed from molecular building blocks having an inclined property that is the same as the added functionality of the SOF; or from molecular building blocks, and the added functionality of the SOF does not arise from an inclined property of the molecular building blocks. The SOF further comprises secondary component, where the secondary component attenuates the added functionality of the SOF; secondary component, where the secondary component enhances the added functionality of the SOF. In the SOF, the segments consists of segments having an identical structure and the linkers consists of linkers having an identical structure, where the segments that are not at the edges of the SOF are connected by linkers to at least three other segments; the segments consists of segments having an identical structure and the linkers consists of linkers having an identical structure, where the segments that are not at the edges of the SOF are connected by linkers to at least three other segments; the segments comprises at least a first and a second segment that are different in structure, and the first segment is connected by linkers to at least three other segments when it is not at the edge of the SOF; the segments comprises at least a first and a second segment that are different in structure, and the first segment is connected by linkers to at least three other segments when it is not at the edge of the SOF; or the segments comprises at least a first and a second segment that are different in structure, and the first segment is connected by linkers to at least three other segments when it is not at the edge of the SOF. The SOF is formed from molecular building blocks having an inclined property selected from hydrophobic added functionality, superhydrophobic added functionality, hydrophilic added functionality, lipophobic added functionality, superlipophobic added functionality, lipophilic added functionality, photochromic added functionality, and electroactive added functionality. Preferred Process: In the process, the inclined property of the molecular building blocks is the same as the added functionality of the SOF; the added functionality of the SOF is not an inclined property of the molecular building blocks; the step of promoting change of the wet film to form a dry SOF with an added functionality enhances the inclined property of the molecular building blocks; and the step of promoting change of the wet film to form a dry SOF with an added functionality attenuates the inclined property of the molecular building blocks. EXAMPLE - No suitable example given.