NOVELTY - Fabricating a component of an organic optoelectronics device involves treating a surface of a polydimethylsiloxane (PDMS) stamp with organic solvent; spin-coating a first polymer film onto the surface of the PDMS stamp to coat the first polymer film onto the surface; and transferring the first polymer film from the PDMS stamp to a target surface. The method further involves annealing the first and second polymer films.    USE - For fabricating component of organic optoelectronics devices (claimed) such as multi-layer devices, LEDs, thin-film transistors (TFTs) and solar cells.    ADVANTAGE - The organic solvent cleans the surface and eliminates stress on the PDMS surface. Pretreatment of the PDMS surface with the organic solvent combined with a dry transfer process provides an easier way for fabrication of organic photoelectronics and offers unique advantages such as reduced cost, flexibility, reduced weight, and an improved eco-process. The method eliminates the need for any unwanted molecules and the damage that they can potentially cause on bottom films, which results from the preceding film during the transfer process. As a result, a stable, fast and reproducible way is achieved to fabricate organic optoelectronic multi-layer devices. The method eliminates the necessity for plasma treatment, and any possible damage to the PDMS surface such that full control over the chemical composition and film thickness of each layer is provided. The method is implemented in a non-vacuum environment, and the multi-layer structure can be achieved by transferring the polymer from the PDMS stamp and eliminates the necessity to include an extra supporting layer for film transfers from the PDMS surface to the target surface. As a result, PDMS stamps are achieved that can be reused for tens of layers. The method also permits the easy formation of a large coverage area having a uniform polymer film on the PDMS stamp surface. The optimum contact between the preceding layer and the successive layer can be achieved. Devices made by PDMS transferring methods provide higher performances than devices made by conventional spin coating methods, mainly because of larger interfaces and surface roughnesses that could be controlled by PDMS surface modification for the further enhancement of the device performance by higher interface area. Method provides a way to control and provide the optimum morphology for each polymer in each single layer. The devices exhibit better performance than most small molecule bi-layer solar cells made via thermal evaporation and exhibit better performance in comparison to devices made by other polymer transfer techniques.