NOVELTY - A hierarchical structured anode has an electroconductive glass and dye absorbed layer coated on the electroconductive glass. The dye absorbed layer is titania-semiconductor hierarchy film. The primary structure of dye absorbed layer is titania nanofiber and/or titania nanotube. The secondary structure of dye absorbed layer is semiconductor nano-grain, semiconductor nano-bar, and/or semiconductor nano-line which are formed by semiconductor nanofiber and/or semiconductor nanotube.    USE - Hierarchical structured anode is used for dye sensitized solar battery used for capacitors, rectifiers, detectors, switching devices, and light-sensitive or temperature-sensitive devices.    ADVANTAGE - The dye sensitized solar battery using hierarchical structured anode has excellent dye absorbing capacity, photoelectric conversion efficiency, and high specific surface area.    DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for manufacture of hierarchical structured anode. Organic titanium alkoxide (in ml) (1-10) is added to absolute ethyl alcohol (10-20), stirred uniformly, and titania sol solution is formed by adding acetic acid (0.1-1.5) and stirring. The titania sol solution is in the form of yellowish transparent clear solution. An acetate solution (0.5-2 g) is dissolved in absolute ethyl alcohol (10-20) to obtain transparent clear acetate solution. The obtained titania sol solution (0.1-2) is added to obtained acetate solution (0.1-2) to obtain titania-acetate mixed solution in the form of yellow transparent clear solution. The obtained mixed solution (0.1-3) is added to polymer ethanol solution (5-20) having concentration of 15-40 weight% and stirred for 120-180 minutes to obtain titania-acetate-polymer spinning solution. A titania-acetate-polymer compound nanofiber film is formed on conductive glass using titania-acetate-polymer spinning solution by static spinning method. The thickness of titania-acetate-polymer compound nanofiber film is 1-20 microns. The obtained titania-acetate-polymer compound nanofiber film-coated conductive glass (0.1-3 g) is immersed in oxalic acid-ethanol solution, deposited into a table concentrator at 30-70 degrees C, reacted for 1-24 hours, cooled to room temperature, cleaned, dried, heated the room temperature to 400-800 degrees C at speed of 1-10 degrees C/minute and roasted for 1-4 hours at constant temperature to obtain conductive glass whose surface is precipitated with titania-semiconductor hierarchy film. The volume proportion of oxalic acid with respect to ethanol is 100:0-100. The obtained conductive glass is heated in an oven at 80 degrees C, dried, added to 0.1-1 mmol/L light sensitization agent solution, immersed for 0.5-10 hours and washed using absolute ethyl alcohol to obtain hierarchical structured anode.