TECHNOLOGY FOCUS - INORGANIC CHEMISTRY - Preferred Atom: The metal atom is transition metal atom belonging to IV-VI period of periodic table, and is preferably titanium, vanadium, manganese, iron, cobalt, nickel, copper, zinc, niobium, molybdenum, ruthenium, rhodium, palladium, silver, tantalum, tungsten, rhenium, osmium, iridium, platinum or gold. Preferred Method: The mixture containing the metal complex, carbon support and an organic compound having boiling point of 200 degrees C or more or organic compound having thermal-polymerization start temperature of 250 degrees C or less, is modified by heating at 200-1200 degrees C.    TECHNOLOGY FOCUS - ORGANIC CHEMISTRY - Preparation (Disclosed): A diamino naphthalene derivative and nitrogen-containing compound of formula (IV) are condensed, and subjected to dehydrogenation to manufacture cyclic compound.R1,R2=H or substituent chosen from halo, hydroxy, carboxy, mercapto, sulfo, nitro, phospho, tri(1-4C alkyl)silyl, 1-50C linear, branched or cyclic alkyl, 1-50C linear, branched or cyclic alkoxy and 6-60C aromatic group;andR"=R'.Preferred Compound: The cyclic compound is preferably of formula (II) or (III), more preferably (III).R3-R5=R1;X1,X2=-O-, -S-, or -N(R1')-;R1'=R1;andR"'=R'. SPECIFIC COMPOUNDS - 15 cyclic compounds e.g. 4,11,15,22-tetra-tert-butyl-39,41-dioxa-8,34,37-triazadecacyclo(23.8.4.12,6.17,10.19,13.116,19.120,24.028,36.031,35.017,40)dotetraconta-1(34),2(42),3,5,7,9,11,13(40),14,16,18,20(38),21,23,25(37),26,28(36),29,32-nonadecaene-38,42-diol of formula (A) 4,11,15,22-tetramethyl-39,41-dioxa-8,18,34,37-tetraazadecacyclo(23.8.4.12,6.17,10.19,13.116,19.120,24.028,36.031,35.017,40)dotetraconta-1(34),2,4,6(42),7,9,11,13(40),14,16,18,20,22,24(38),25(37),26,29,31(35),32-nonadecaene-38,42-diol, 8,18,34,37,39,41-hexaazadecacyclo(23.8.4.12,6.17,10.19,13.116,19.120,24.028,36.031,35.017,40)dotetraconta-1(34),2,4,6(42),7,9,11,13(40),14,16,18,20,22,24(38),25(37),26,29,31(35),32-nonadecaene-38,42-diol, 11,15-dimethyl-39-oxa-41-thia-8,18,34,37-tetraazadecacyclo(23.8.4.12,6.17,10.19,13.116,19.120,24.028,36.031,35.017,40)dotetraconta-1(34),2,4,6(42),7,9,11,13(40),14,16,18,20,22,24(38),25(37),26,29,31(35),32-nonadecaene-38,42-diol and 4,22,41-trimethyl-39-oxa-8,18,34,37,41-pentaazadecacyclo(23.8.4.12,6.17,10.19,13.116,19.120,24.028,36.031,35.017,40)dotetraconta-1(34),2,4,6(42),7,9,11,13(40),14,16,18,20,22,24(38),25(37),26,29,31(35),32-nonadecaene-38,42-diol are disclosed.    EXAMPLE - 1,8-Diamino-2,7-dihydroxy naphthalene (20 mg) and aldehyde (20 mg) were mixed. Xylene (5 ml) and p-toluenesulfonic acid (5 mg) were added. The mixture was stirred at 120 degrees C for 2 hours, and cooled to room temperature. Palladium/carbon catalyst (50 mg) was added and stirred at 150 degrees C for 4 hours. The solution was cooled to room temperature, and filtered to obtain cyclic compound.