NOVELTY - Fluoropolymer hybrid organic/inorganic composite comprises inorganic domains, where the hybrid is obtained by reacting at least one fluoropolymer comprising recurring units derived from at least one (meth)acrylic monomer compound and at least one metal compound.    USE - The fluoropolymer hybrid organic/inorganic composite is useful: for coating a glass and/or ceramic surface; as raw materials for the manufacture of membranes for electrochemical applications and/or separation processes; as electroluminescent materials in photovoltaic or organic light emitting devices; for manufacturing multilayer structures (all claimed); and in optic exploit.    ADVANTAGE - The fluoropolymer hybrid organic/inorganic composite: exhibits improved scratch resistance, hydrophilicity, ion conductivity, and electro-optic properties, such as notably hole transport capabilities, electron transport capabilities and chronophers; and has good adhesion, barrier properties and corrosion protection.    DETAILED DESCRIPTION - Fluoropolymer hybrid organic/inorganic composite comprises inorganic domains, where the hybrid is obtained by: reacting at least one fluoropolymer comprising recurring units derived from at least one (meth)acrylic monomer compound of formula (R1-C(-R2)=C(-R3)(-C(=O)-O-ROH)-); and at least one metal compound of formula (X4-m-AY1m), where ROH is a hydrogen atom or 1-5C hydrocarbon moiety comprising at least one hydroxyl group (polymer (F1)), and the inorganic domains are grafted to the polymer (F1) through reaction of at least a fraction of the ROH groups of the monomer with at least a fraction of metal compound.    R1-R3 = H or 1-3C hydrocarbyl;    m = 1-4;    A = metal consisting of Si, Ti and Zr;    Y1 = hydrolysable group; and    X = hydrocarbyl, optionally comprising one or more functional groups.    INDEPENDENT CLAIMS are included for:    (1) manufacturing the fluoropolymer hybrid organic/inorganic composite, comprising providing a mixture of the fluoropolymer, reacting the polymer (F1) with at least a fraction of the metal compound to obtain a grafted polymer comprising pendant having a structure of formula (-Y1(m-1)AX(4-)m), and hydrolyzing and/or polycondensing metal compound and/or the pendant; and    (2) use of the fluoropolymer hybrid organic/inorganic composite for the treatment of glass and/or of ceramic materials.