TECHNOLOGY FOCUS - ORGANIC CHEMISTRY - Preparation (Disclosed): Preparation of (I) comprises reacting (II) with substituted aryl compounds of formula (R9-Q-X).X = OH, halo (preferably F, Cl or Br) or alkoxy. Preferred Definitions:    A = x-CH2-C(=O)-;    T = CH;    G = S;    Y1 = H;    Y2 = CH;    Q = -C(=O)-z;    n = 2;    p = 1;    R1 = substituted pyrazole of formula (A) or substituted phenyl of formula (B);    R22-R25 = H, halo, CH3 or halomethyl;    R2-R8 = H; and    R9 = phenyl (optionally substituted by OH (at ortho position) and optionally substituted one or two further substituents).    ACTIVITY - Fungicide; Antibacterial. The fungicidal activity of (I) was tested against Plasmopara viticola in grape leaf disc. The result showed that 1-(2-(1-(2-(5-methyl-3-trifluoromethyl-pyrazol-1-yl)-acetyl)-piperidin-4-yl)-thiazol-4-yl)-3-phenyl-urea exhibited at least 80% disease control at 200 ppm.    MECHANISM OF ACTION - None given.    ADMINISTRATION - Application of (I) is 5 g to 2 kg/hectare (preferably 20-600 g/hectare) by spraying, atomizing, dusting, scattering, coating or pouring.    SPECIFIC COMPOUNDS - 12336 Compounds (I) are disclosed e.g. 1-(2-(1-(2-(5-methyl-3-trifluoromethyl-pyrazol-1-yl)-acetyl)-piperidin-4-yl)-thiazol-4-yl)-3-phenyl-urea of formula (Ia), 1,2,3,4-tetrahydro-naphthalene-1-carboxylic acid (2-(1-(2-(5-methyl-3-trifluoromethyl-pyrazol-1-yl)-acetyl)-piperidin-4-yl)-thiazol-4-yl)-amide, 2-(1-(2-(5-methyl-3-trifluoromethyl-pyrazol-1-yl)-acetyl)-piperidin-4-yl)-thiazol-4-yl)-carbamic acid phenyl ester, N-(2-(1-(2-(5-methyl-3-trifluoromethyl-pyrazol-1-yl)-acetyl)-piperidin-4-yl)-thiazol-4-yl)-benzene sulfonamide and N-(2-(1-(2-(2,5-dimethyl-phenyl)-acetyl)-piperidin-4-yl)-thiazol-4-yl)-2-phenyl-propionamide.    EXAMPLE - A solution of phenylisocyanate (30 mu l) in tetrahydrofuran (1 ml) was added dropwise to a solution of 1-(4-(4-amino-thiazol-2-yl)-piperidin-1-yl)-2-(5-methyl-3- trifluoromethyl-pyrazol-1-yl)-ethanone (100 mg) in tetrahydrofuran (5 ml) at 0 degrees C. After stirring, methanol (1 ml) was added to the reaction mixture with stirring and the solvents were evaporated and the residue was triturated with diethylether (5 ml) to induce precipitation. The resulting solid was filtered and dried under vacuum to give 1-(2-(1-(2-(5-methyl-3-trifluoromethyl-pyrazol-1-yl)-acetyl)-piperidin-4-yl)-thiazol-4-yl)-3-phenyl-urea (105 mg, 79%).