TECHNOLOGY FOCUS - INORGANIC CHEMISTRY - Preferred Components: The first off-gas stream comprises pressure swing adsorption tail gas consisting of carbon monoxide, un-reacted hydrocarbons, carbon dioxide, some portion of hydrogen, nitrogen and argon impurities of the oxygen stream. The syngas stream comprises hydrogen, carbon monoxide and carbon dioxide.    TECHNOLOGY FOCUS - ORGANIC CHEMISTRY - Preferred Components: The second biofuels process is a first generation bio-ethanol process, which produces a bio-ethanol stream, and the hydrogen production unit producing the hydrogen stream and the steam stream. The pyrolysis unit produces the char stream and a bioliquid stream. The low pressure hydrotreating component produces the hydrocarbon stream. The high pressure hydrotreating component produces the steam stream. The distillation unit produces a green gasoline stream and a green diesel stream from the bioliquid stream. The hydrogen production unit: has a furnace, a process effluent stream (207), a flue gas stream, a feed stream and a fuel stream; and consists of a partial oxidation unit. The feed stream is the hydrocarbon stream, is combined with the steam stream produced from the hydrogen production unit, and is fed to the furnace. The fuel stream is the char stream, and indirectly exchanges heat with a second feedwater stream in a second waste heat boiler to produce the steam stream. The process effluent stream indirectly exchanges heat with a first feed water stream in a first waste heat boiler. The process further comprises contacting the process effluent with a catalyst in a water gas shift reactor to convert carbon monoxide to hydrogen and carbon dioxide for producing a shift effluent, indirectly exchanging heat between the shift effluent and a first feed water stream in a first waste heat boiler to produce the steam stream for producing a cooled shift effluent, feeding the cooled shift effluent into a pressure swing adsorption (PSA) unit to separate hydrogen from carbon monoxide, un-reacted hydrocarbons and carbon dioxide for producing the hydrogen stream and a PSA tail gas stream, sending the hydrogen stream to the high pressure hydrotreating component, and sending the PSA tail gas to the furnace, where the PSA tail gas is used as fuel for the furnace in combination with the char stream. The high pressure hydrotreating component is a bioliquid hydrotreater. A portion of the steam stream is fed to the furnace. A portion of the steams stream is exported to the second biofuels process. The char stream and the hydrocarbon stream are introduced as feed. An oxygen stream is generated by air separation in a cryogenic process, and is introduced the oxygen stream into the partial oxidation unit. The oxygen stream, the char stream and the hydrocarbon stream are combined in the partial oxidation unit for producing a syngas stream. The syngas stream is cooled in a first heat exchanger for creating a cooled syngas stream. The cooled syngas stream is combined with a water stream or a steam stream for producing a wet syngas stream. The wet syngas stream is introduced into a water gas shift reactor, where a water gas shift reaction is promoted by contact with a catalyst for producing a shifted syngas stream. The shifted gas stream and a feed water stream exchange heat in an indirect contact a waste heat boiler to produce a steam stream for producing a cooled shifted syngas stream. The cooled shifted syngas stream is further cooled in an air cooler for producing a further cooled shifted syngas stream. The further cooled shifted syngas stream is introduced into a first absorption unit, where a hydrogen stream is separated from a first off-gas stream. The catalyst promotes a conversion of carbon monoxide to hydrogen to produce a shifted syngas with 90% of the carbon monoxide converted to hydrogen. The first adsorption unit consists of a pressure swing adsorption unit producing hydrogen with a purity of greater than 99.5%. The hydrogen stream is sent to the bioliquid hydrotreater. A part of the first off-gas stream is compressed in a compressor for producing a compressed off-gas stream and a remainder stream. The compressed off-gas stream is recycled to the first adsorption unit for further recovery of hydrogen or sent to a second adsorption unit for further recovery of hydrogen and for producing a second off-gas stream and a second hydrogen stream. The remainder stream and the second off-gas stream are combined to form a combined off-gas stream. The combined off-gas stream is sent to the bioliquid hydrotreater to be used as fuel in furnaces within the bioliquid hydrotreater and/or the fractionation section. The second adsorption unit is a PSA. The first adsorption unit comprises an absorber for the removal of carbon dioxide and for purification of hydrogen. The carbon dioxide is removed in the absorber by contacting the cooled shifted syngas stream with an activated methyldiethanolamine (MDEA) stream or similar solvent stream for producing a purified hydrogen stream from an overhead of the absorber and a rich solvent stream from the bottom of the absorber. The rich solvent stream is sent to a regenerator, where the steam stream is used to regenerate the solvent stream for producing a regenerated solvent stream that is returned to the absorber. The purified hydrogen stream is heated in a heat exchanger for producing a heated purified hydrogen stream that is sent to a methanation reactor, where the methanation reactor is contacted with a catalyst to promote the reaction of remaining carbon monoxide and carbon dioxide to produce a methane stream and a further purified hydrogen stream. The further purified hydrogen stream has a purity of greater than 97%, and is sent to the high pressure hydrotreating component.