TECHNOLOGY FOCUS - INORGANIC CHEMISTRY - Preferred Composition: The inorganic metalized film comprises indium-tin oxide, indium-zirconium oxide, silicon oxide (SiOx, where x is not defined) or aluminum oxide (AlOx).    TECHNOLOGY FOCUS - METALLURGY - Preferred Component: The barrier film is metallic foil having thickness of 1-200 mu m or inorganic metalized film. The metallic foil is aluminum foil, copper foil or stainless steel foil.    TECHNOLOGY FOCUS - ORGANIC CHEMISTRY - Preferred Components: A silicon-oxygen bond, titanium-oxygen bond, zirconium-oxygen bond or aluminum-oxygen bond are formed in the interface of the primer layer and barrier film. A hydrogen bond is formed in the interface of the primer layer and barrier film. The polymerizable monomer is (meth)acrylic monomer, (meth)acrylamide-based monomer and vinyl monomer. The (meth)acrylic monomer is chosen from 21 compounds e.g. methyl (meth)acrylate, ethyl (meth)acrylate, propyl (meth)acrylate, n-butyl (meth)acrylate and s- butyl (meth)acrylate. The silane coupling agent is chosen from 16 compounds e.g. vinyltrimethoxysilane, vinyltriethoxysilane, vinyl tripropoxysilane, vinyl triisopropoxy silane and vinyltributoxysilane. The titanate coupling agent is chosen from 16 compounds e.g. isopropyl triacryloyl titanate, isopropyl trimethacryl titanate, isopropyl trioleyl titanate, tetra(diallyloxymethyl)-1-butoxytitanium di(ditridecyl)phosphate and isopropyl triethanolamine titanate. The aluminum-based coupling agent is aluminum III diisopropoxide-ethylacetoacetate or aluminum-2,4-pentane dionate.    TECHNOLOGY FOCUS - POLYMERS - Preferred Composition: The multilayered film further has an inorganic metalized film (12) having thickness of 1-1000 nm, fluorinated polymer coating layer (14) containing pigment, filler, UV stabilizer, thermal stabilizer, dispersing agent or barrier particles and having thickness of 3-50 mu m, substrate (11) having thickness of 50-500 mu m and adhesive layer between barrier film and material. The acrylic copolymer is obtained using polymerizable monomers including (meth)acryl group and (meth)acrylamide group, and coupling agent in mixing ratio of 1:99-99:1. The fluorinated polymer is chosen from homopolymer or copolymer of 14 compounds e.g. vinylidene fluoride, vinyl fluoride, tetrafluoroethylene, hexafluoropropylene and chlorotrifluoroethylene, and has weight average molecular weight of 50000-1000000 and melting point of 80-175 degrees C. The substrate is made of aluminum, iron, polyethylene terephthalate, polyethylene naphthalate or polybutylene terephthalate. Preferred Property: The thickness of primer layer is 0.01-5 mu m.