NOVELTY - Processing biomass material, comprises: introducing biomass material to a pressurized compartment of a solventless recovery system; contacting biomass material with superheated vapor stream in the compartment to vaporize a portion of an initial liquid content in the biomass material; separating vapor component and solid component from heated biomass material; retaining a portion of the gas component for use as part of superheated vapor stream; discharging solid component from the system; and contacting a portion of solid component with a solution adapted to facilitate saccharification.    USE - The method is useful for processing biomass material to produce VOCs (claimed) such as esters, ketones, alcohols (ethanol), aldehydes, hydrocarbons and terpenes.    ADVANTAGE - The method: utilizes the readily available fermentable sugar and production of fermentable sugar from further processing of lignocellulosic material in the biomass material; utilizes the solventless recovery system that can operate year-round using only a four-month harvest window, thus reducing capitals cost; allows for economical and efficient production of VOCs by reducing costs of storage and transportation, short harvest windows, quick degradation of sugars, and large investment in equipment. The solid component allows for better saccharification, particularly pretreatment and enzymatic hydrolysis, as compared to other biomass feedstock sources, and achieves the same or better glucose production after pretreatment with alpha -hydroxysulfonic acid and enzymatic hydrolysis without agitation or mixing (such as stirring), thus enabling for a simpler and more economical scale up (such as commercial scale) operations. The prepared biomass material allows for continuous production of VOCs without dependence on the length of the harvest, thus eliminating or minimizing down time of a recovery plant in traditional just-in-time harvest and recovery processes. The produced volatile organic products remain stable for up to 700 days without significant degradation.    DETAILED DESCRIPTION - Processing a biomass material, comprises: introducing a biomass material to a pressurized compartment of a solventless recovery system, where the biomass material contains at least one volatile organic compound (VOC); contacting the biomass material with a superheated vapor stream in the pressurized compartment to vaporize at least a portion of an initial liquid content in the biomass material, where the superheated vapor stream comprises at least one VOC; separating a vapor component and a solid component from the heated biomass material, where the vapor component comprising at least one VOC; retaining at least a portion of the gas component for use as part of the superheated vapor stream; discharging the solid component from the recovery system; and contacting at least a portion of the solid component with a solution adapted to facilitate saccharification.