NOVELTY - Metal organic framework (MOP) comprises a polymeric crystalline structure comprising a coordination product of a metal component comprising a metal center which is zinc oxide tetrahedron (Zn4O), zinc (Zn2), copper (Cu2), vanadium oxide (V3O3) or zirconium oxide (Zr6O6), an organic ligand component of any one of approximately 90 ligands e.g. 5,5'-(4,4'-(5-(3-(3,5-dicarboxyphenyl)-3H-pyrazol-5-yl)-1,3-phenylene)bis(1H-1,2,3-triazole-4,1-diyl))diisophthalic acid, benzene-1,3,5-tricarboxylic acid, naphthalene-2,6-dicarboxylic acid and/or 1,2-di(pyridin-4-yl)ethyne, and optionally a solvent.    USE - The MOP is useful in a container (cylindrical or non-cylindrical configurations) for at least one of up-taking, storing and releasing at least one gas and in a method of gas sorption, where the gas comprises methane and the container is incorporated into a gas storage system and a fuel cell of an automotive vehicle (all claimed).    ADVANTAGE - The MOP provides the methane storage of at least 240v(STP)/v under at least 65 bar, and thus it can be used for high pressure methane storage.    DETAILED DESCRIPTION - Metal organic framework (MOP) comprises a polymeric crystalline structure comprising a coordination product of a metal component comprising a metal center which is zinc oxide tetrahedron (Zn4O), zinc (Zn2), copper (Cu2), vanadium oxide (V3O3) or zirconium oxide (Zr6O6), an organic ligand component of any one of approximately 90 ligands e.g. 5,5'-(4,4'-(5-(3-(3,5-dicarboxyphenyl)-3H-pyrazol-5-yl)-1,3-phenylene)bis(1H-1,2,3-triazole-4,1-diyl))diisophthalic acid, (1,1';4',1'')terphenyl-3,5,3'',5''-tetracarboxylic acid, anthracene-9,10-dicarboxylic acid, benzene-1,3,5-tricarboxylic acid, naphthalene-2,6-dicarboxylic acid and/or 1,2-di(pyridin-4-yl)ethyne, and optionally a solvent. INDEPENDENT CLAIMS are also included for:    (1) 5,5'-(4,4'-(5-(3-(3,5-dicarboxyphenyl)-3H-pyrazol-5-yl)-1,3-phenylene)bis(1H-1,2,3-triazole-4,1-diyl))diisophthalic acid and its salts;    (2) a MOF building block comprising 5,5'-(4,4'-(5-(3-(3,5-dicarboxyphenyl)-3H-pyrazol-5-yl)-1,3-phenylene)bis(1H-1,2,3-triazole-4,1-diyl))diisophthalic acid and the metal component;    (3) a method of gas sorption, comprising providing the MOF and contacting the MOF and a gas under at least one of a pressure and a temperature sufficient for gas sorption with the MOF;    (4) a method of using a MOP building block comprising the ligand component for methane storage, comprising providing a MOP comprising the building block and contacting the MOF and methane under at least one of a pressure and a temperature sufficient for methane storage with the MOF; and    (5) a container for at least one of up-taking, storing and releasing at least one gas, comprising at least one of an inlet component and an outlet component, a pressure control component to maintain a gas under pressure in the container, and a MOF material comprising the MOF and optionally a gas.