NOVELTY - A nickel substrate is mechanically polished to remove oxide on the surface, obtained substrate is subjected to ultrasonic shaking, chemical degreasing is carried out, resultant product is washed using de-ionized water, and naturally dried. Pulse electro-deposition is carried out using obtained nickel substrate as working electrode, nickel plate as counter electrode, and nickel-molybdenum-phosphorus plating solution. Obtained nickel substrate is washed using deionized water to remove residual plating solution, and dried naturally, to obtain hydrogen evolution electrode.    USE - Preparation of hydrogen evolution electrode used for electrocatalysis hydrogen evolution in chlor-alkali industry, solar water electrolysis hydrogen and electrolytic water industry.    ADVANTAGE - The method enables efficient and economical preparation of hydrogen evolution electrode by simple process.    DETAILED DESCRIPTION - A nickel substrate is mechanically polished to remove oxide on the surface, obtained substrate is subjected to ultrasonic shaking for 20 minutes and chemical degreasing is carried out using alkali solution containing sodium sulfate (in g/L) (45), sodium carbonate (45) and sodium chloride (45), resultant product is washed using de-ionized water, and naturally dried after immersing in absolute ethanol solution. Pulse electro-deposition is carried out at 20-60 degrees C for 5-300 seconds using obtained nickel substrate as working electrode, nickel plate as counter electrode, and nickel-molybdenum-phosphorus plating solution containing aqueous solution of nickel salt (20-60), aqueous solution of molybdic acid salt (10-50), aqueous solution of sodium hypophosphite (10-60), aqueous solution of trisodium citrate (20-150), and aqueous solution of sodium chloride (10-300). The nickel-molybdenum-phosphorus plating solution has pH of 10. The pulse peak current density, pulse conduction time and pulse off-time during pulse electro-deposition is 10-30 A/dm2, 1-10 mseconds, and 5-50 mseconds, respectively. Obtained nickel substrate is washed using deionized water to remove residual plating solution, and dried naturally, to obtain hydrogen evolution electrode.