TECHNOLOGY FOCUS - POLYMERS - Preferred Composition: The composition further comprises: a thermal or photo initiator; one or more component comprising fillers, UV absorbers, UV stabilizers, cure accelerators, pigments, dyes, antimicrobial agents, biocides, surfactants, conductive fillers, non-reinforcing fillers, plasticizers, tackifiers, mold release agents, adhesion promoters, compatibilizers, pharmaceutical excipients, surfactants, antistatic agents, solvents, flattening agents and thixotropic agents; an initiator to facilitate reaction between the silicone ionomer and the unsaturated olefin reactive component; 0.001-50 pts. wt. of a cationic photoinitiator; and 0-99 pts. wt. of fluorinated alcohols, polyols, acrylates, epoxies or vinyl ethers. The composition optionally comprises a photosensitizer comprising benzoin methyl ether or benzophenone/dimethyl ethanol amine. The composition comprises: 0-99 pts. wt. of acrylate derivatives comprising methacrylate, butylacrylate, propylacrylate, N,N-dimethylacrylamide, methacrylic acid, N-isopropyl acrylamide, 2-hydroxy-ethyl-methacrylate and methacrylic acid, 3-(tris(trimethylsiloxy)silyl)propyl methacrylate, acrylate and methacrylate functional carbosilane molecules, hexafunctional urethane acrylates, dipentaerythritol pentaacrylate, ethoxylated pentaerythritol tetraacrylate, di-trimethylolpropanetetraacrylate, pentaerythritol triacrylate, trimethylolpropane triacrylate, ethoxylated trimethylolpropane triacrylate, butanediol diacrylate, tripropylene glycol diacrylate, trimethylolpropane trimethacrylate, oligofunctional urethane acrylates, tetraacrylate monomer and/or polyester acrylate oligomers or its isomers; 0-99 pts. wt. of an unsaturated olefin reactive component comprising styrenic monomers and oligomers and/or vinyl monomers and oligomers; 0-99 pts. wt. of a thiol-containing derivative; and a fluorinated aliphatic 1-10C-alcohol. The free radical polymerized composition is an emulsion. The free radical polymerized composition or solution or bulk polymerized composition comprises monomers, prepolymers, crosslinkers, initiators, surfactants, co-surfactants, rheology modifiers, solvents, co-solvents and at least one phase immiscible with the the organosiloxane composition. The free radical polymerized composition is in an immiscible phase, which is an aqueous phase, where the emulsion is a microemulsion, a miniemulsion or a ternary emulsion. The healthcare application comprises one or more additional agents comprising metals, metal ions, bioactives, antiacne agents, antiageing agents, ant-caries agents, antifungal agents, antimicrobial agents, antioxidants, anticancer, antiviral, antiinflammatory, anticoagulants, hemostatic agents, exfoliants, hormones, enzymes, medicinal compounds, biocides, external analgesics, oral care agents, oral care drugs, ophthalmic drugs, oxidizing agents, reducing agents, skin protectants, essential oils, insect repellents, UV light absorbing agents, solar filters, pigments, hydrating agents and/or vitamins. The healthcare application is useful in combination with one or more of wound dressings, dressings for scar reduction, drug delivery devices, medical tubing, clinical surfaces, pacemaker leads, pressure sensitive adhesives, wound healing patches, wound dressings, scar reduction patches, wound management devices, wound healing gels, wound dressing adhesives, transdermal patches, iontophoresis devices, scaffolds for tissue engineering, antimicrobial devices, ophthalmic devices, bioinserts, surgical devices, medical devices, medical storage devices, plugs, prostheses and body implants, reconstructive devices and medical adhesives. Preferred Components: The initiator comprises: 0.001-50 pts. wt. of photoinitiators comprising benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin propyl ether, benzoin-n-butyl ether, benzoin isobutyl ether, acetoin, butyroin, toluoin, benzil, benzophenone, para-methoxybenzophenone, 2,2-diethoxyacetophenone, alpha - alpha -dimethoxy- alpha -phenylacetophenone, methylphenyl glyoxylate, ethyphenyl glyoxylate, 4,4'-bis- (dimethylaminobenzophenone), propiophenone, acetophenone, 1-hydroxycyclohexyl phenyl ketone, 2,2-diethoxyacetophenone, ethylphenylpyloxylate, phenanthraquinone, and 2-hydroxy-2-methyl-1-phenyl-propan-1-one, tetramethylthiuram monosulfide, tetramethylthiuram disulfide, azobisisobutyronitrile, azobis-2,4-dimethylvaleronitrile, benzoyl peroxide, di-tert-butyl peroxide, 7-chlorothioxanthone, 2,4-diethylthioxanthone, 2,4-diisopropylthioxanthone and/or acylophosphine oxide photoinitiators; sulfur compounds such as tetramethylthiuram monosulfide and tetramethylthiuram disulfide; azo compounds such as azobisisobutyronitrile and azobis-2,4-dimethylvaleronitrile; and organic peroxide compounds such as benzoyl peroxide, dicumyl peroxide, methyl ethyl ketone peroxide, acetone peroxide and di-tert-butyl peroxide; thioxanthone photoinitiators such as 7-chlorothioxanthone, 2,4-diethylthioxanthone and 2,4- diisopropylthioxanthone; and acylophosphine oxide photoinitiators, proprietary free radical initiator compositions such as Irgacure (RTM: Photoinitiator), VAZO (RTM: 2,2'-Azodi(2-methylbutyronitrile)) or Darcure (RTM: 1-(4-isopropylphenyl)-2-hydroxy-2-methyl-propanone). The cationic photoinitiator comprises diaryliodonium salts of formula (R292I+Y1-), triarylsulfonium salts of formula (R293S+Y1-), triarylselenonium salts of formula (R293Se+Y1-), tetraarylphosphonium salts of formula (R294P+Y1-) or aryldiazonium salts of formula (R294N+Y1-).R29 = aryl group; andY1 = anion comprising from SbF6-, AsF6-, PF6-, BF4-, HSO4- or ClO4-. EXAMPLE - No suitable example given.