TECHNOLOGY FOCUS - INORGANIC CHEMISTRY - Preferred Components: The alkali or alkaline earth metal alkoxide is sodium methoxide.    TECHNOLOGY FOCUS - ORGANIC CHEMISTRY - Preferred Composition: (A1) further comprises: a free radical initiator (which is peroxides, peroxy compounds, UV initiators and/or heat initiators) or moisture curing catalyst; and an additive comprising stabilizers, accelerators, catalysts, fillers, moisture scavengers, initiators, solvents, crosslinkers, coloring agents and/or rheology modifiers. Preferred Components: (I) is a monomer or an oligomer. (I) is grafted onto a backbone. (I) includes a surfactant moiety. (I) is siloxy fluoroalkyl compounds of formula ((R9O)3-Si-O-CH2-(CF2)4-H) (II) or substituted dicarbonyl fluoroalkyl compounds of formula (H-(CF2)4-CH2-O-C(=O)-R3-C(=O)-O-CH2-(CF2)4-H) (IV). (B2) includes at least one reactive terminal group.R9 = H and/or 1-20C alkyl.The fluorinated alkanol is 2,2,3,3,4,4,5,5-octafluoropentanol. The organosilane compound is tetra alkoxysilane. The ligand is primary, secondary or tertiary alkyl amines and/or linear, branched and dendritic polyamines and polyamides. The initiator in forming a fluorinated curable composition is a halogen-containing compound. The catalyst is tris(2-dimethylaminoethyl)amine. The free radical initiator in the controlled radical polymerization process, is peroxides, hydroperoxides, azobisisobutyronitrile and/or peresters or ketene acetal initiator. The ketene acetal initiator is silyl ketene acetal. At least one of methacryloxy, hydroxy, epoxy, alkoxy, amino, isocyanate, vinyl, allyl, siloxy, halo or carbamate is present in the resultant polymerized product of the controlled radical polymerization process. The octofluoropentyl group includes at least one hydroxy, siloxy, epoxy, cyano, halo, isocyanate, (meth)acryloxy, aceto, cyanoacrylate, cyanoacetate, alkyl ether, epoxyether or vinyl ether. The reactive composition further includes: a cure system; an additional reactive component comprising monomers, polymers, oligomers and/or reactive diluents; and a surfactant moiety. The cure system is free-radical cure systems, UV-cure systems, moisture cure systems and/or heat cure systems. The diisocyanate compound is ethylene diisocyanate, 1,2-diisocyanatopropane, 1,3-diisocyanatopropane, 1,6-diisocyanatohexane, 1,4-diisocyanatobenzene, para-, meta- or ortho-diisocyanatobenzene, bis(4-isocyanatocyclohexyl) methane, bis(4-isocyanatophenyl) methane, toluene diisocyanate (TDI) e.g. 2,4-TDI, 2,6-TDI, 3,3'-dichloro-4,4'-diisocyanatobiphenyl, tris(4-isocyanatophenyl)methane, 1,5-diisocyanatonaphthalene, hydrogenated toluene diisocyanate, 1-isocyanatomethyl-5-isocyanato-1,3,3-trimethylcyclohexane and/or 1,3,5-tris(6-isocyanatohexyl)biuret. Preferred Process: The method of forming a fluorinated curable composition through controlled polymerization, further comprises adding at least one additional polymerizable component to the vessel. The controlled radical polymerization process further comprises: step of functionalizing the resultant polymerized product, where the functionalized product is an oligomer formed using ATRP; and incorporating an additional reactive component, which is monomers, polymers and/or reactive diluents. The catalyst is slowly added to the reaction mixture at less than or equal to 0 degrees C.    TECHNOLOGY FOCUS - POLYMERS - Preferred Components: The additional polymerizable component includes a monomer, oligomer, polymer and/or reactive diluent. The additional polymerizable component is (meth)acrylates, urethanes, silicones, epoxies and/or olefins. (B2) is part of a polymer or oligomer which is predominantly hydrophobic or predominantly hydrophilic. The reactive composition comprises a room temperature curing silicone, an anaerobic adhesive or sealant and a cleaning fluid. WIDER DISCLOSURE - The substituted fluoroalkyl compounds (I) are also disclosed as new.    SPECIFIC COMPOUNDS - The use of (1-(3-isopropenyl-phenyl)-1-methyl-ethyl)-carbamic acid 2,2,3,3,4,4,5,5-octafluoro-pentyl ester of formula (Ia), (1-(3-(1-isocyanato-1-methyl-ethyl)-phenyl)-1-methyl-ethyl)-carbamic acid 2,2,3,3,4,4,5,5-octafluoro-pentyl ester, diethyl octadecyl 2,2,3,3-tetrafluoropropyl orthosilicate and succinic acid monopentyl ester is specifically claimed as (I).    EXAMPLE - Under nitrogen atmosphere, 2,2,3,3,4,4,5,5-octafluoro-1-pentanol (139 ml), 1-(2-isocyanatopropan-2-yl)-3-(prop-1-en-2-yl)benzene (237 ml) and hexane (700 ml) were charged to a three-neck flask (2l) while stirring. The reaction mixture was then cooled to -5 degrees C by an ice-salt bath. Dibutyltin dilaurate (6.3 g) was added to reaction mixture dropwise. The reaction system temperature was maintained below 0 degrees C during dibutyltin dilaurate addition. Then the mixture temperature was allowed up to room temperature gradually and was stirred at this temperature for 30 hours. After the removal of volatile solvents under vacuum, purified to give (1-(3-isopropenyl-phenyl)-1-methyl-ethyl)-carbamic acid 2,2,3,3,4,4,5,5-octafluoro-pentyl ester (500 g, 79.8%).