TECHNOLOGY FOCUS - POLYMERS - Preferred Components: The di-activated vinyl compound comprises at least one member of methylene malonate, methylene betaketoester or methylene betadiketone. The methylene malonate monomer is of formula (R1-O-C(O)-C(=CH2)-C(O)-R2). The methylene betaketoester monomer is of formula (R3-C(O)-C(=CH2)-C(O)-O-R4). The methylene betadiketone monomer is of formula (R5-C(O)-C(=CH2)-C(O)-R6). The polymerizable composition comprises a multifunctional monomer or oligomer. The multifunctional monomer or oligomer comprises at least two units of formula (W1-C(O)-C(=CH2)-C(O)-W1). The multifunctional monomer or oligomer is a transesterification product of a di-activated vinyl compound with a diol or a polyol. The polymerizable composition comprises a blend of at least one multifunctional monomer or oligomer and at least one mono-functional monomer. The multifunctional monomer or oligomer is present at at least 2 wt.%, preferably at least 10 wt.% of the blend. The reinforcing or filler material comprises at least one of particulates, glass natural and synthetic fiber, woven and non-woven fabric, nanoparticles, carbon, clay, fiberclass, carbon fiber, wood particles, wood shavings, wood flour, alumina, silica, sand, plastics, polycarbonate, acrylonitrile butadiene styrene, aluminized fiberglass, veil mat, fiberglass mat, biaxial cloth, release fabric, carbon fiber cloth, fumed silica, polyethylene fibers, polypropylene fibers, titania or aramid fiber. The article of manufacture comprises at least one thermally sensitive material unable to withstand applied heat of greater than 100 degrees C. The system further comprises: a polymerization activator; and a formulation additive. The polymerization activator is present in or on the reinforcing or filler material. The polymerization activator is present in a pure form, in a dilute form, fugitive or non-fugitive form. The polymerization activator includes a base, a base precursor, a base creator or a base enhancer. The polymerization activator is an organic material, an inorganic material and/or organo-metallic material. The polymerization activator is sodium acetate, potassium acetate, acid salts of sodium, potassium, lithium, copper or cobalt, tetrabutyl ammonium fluoride, chloride or hydroxide, amine whether primary, secondary or tertiary, an amide, salts of polymer bound acids, benzoate salts, 2,4-pentanedionate salts, sorbate salts, propionate salts, secondary aliphatic amines, piperidine, piperazine, N-methylpiperazine, dibutylamine, morpholine, diethylamine, pyridine, triethylamine, tripropylamine, triethylenediamine, N,N-dimethylpiperazine, butylamine, pentylamine, hexylamine, heptylamine, nonylamine, decylamine, salts of amines with organic monocarboxylic acids, piperidine acetate, metal salt of a lower monocarboxylic acid, copper(II) acetate, cupric acetate monohydrate, potassium acetate, zinc acetate, zinc chloroacetate, magnesium chloroacetate, magnesium acetate, salts of acid containing polymers, salts of polyacrylic acid co-polymers. The formulation additive is plasticizers, thixotropic agents, adhesion promoters, antioxidants, light stabilizers, UV stabilizers, fillers, surfactants, wetting agents, viscosity modifiers, extenders, dispersants, antiblocking agents, defoamers, air release agents, antisagging agents, antisetting agents, matting agents, flattening agents, waxes, antimar additives, anti-scratch additives or inert resins. The first and second substrates are same or different materials and are plant-based material, plastic, carbon-based material, metal or glass-based material, paper, oak, Douglass fir, balsa, polyphenylene ether plastic, polycarbonate, silicon, glass, fiberglass, silver coated copper, copper, steel, polypropylene, biaxially oriented polypropylene, monoaxially oriented polypropylene, polyethylene, polyester, polyethylene terephthalate, biaxially oriented polyethylene terephthalate or aluminum. The laminate article of manufacture further comprises at least one thermally sensitive material.Either R1, R2 = 1-15C alkyl, 2-15C alkenyl, halo-(1-15C alkyl), 3-6C cycloalkyl, halo-(3-6C cycloalkyl), heterocyclyl, heterocyclyl-(1-15C alkyl), aryl(1-15C alkyl), heteroaryl, heteroaryl-(1-15C alkyl) or alkoxy-(1-15C alkyl) (all optionally substituted by 1-15C alkyl, halo-(1-15C alkyl), 3-6C cycloalkyl, halo-(3-6C cycloalkyl), heterocyclyl, heterocyclyl-(1-15C alkyl), aryl, aryl-(1-15C alkyl), heteroaryl, 1-15C alkoxy, 1-15C alkylthio, OH, NO2, azido, acyloxy, carboxy, ester or sulfonyl);R1R2 = 5-7 membered heterocyclyl ring (optionally substituted by 1-15C alkyl, halo(1-15C alkyl), 3-6C cycloalkyl, halo(3-6C cycloalkyl), heterocyclyl, heterocyclyl-(1-15C alkyl), aryl, aryl-(1-15C alkyl), heteroaryl, 1-15C alkoxy, 1-15C alkylthio, OH, NO2, azido, acyloxy, carboxy, ester or sulfonyl); eitherR3, R4, R5,R6 = 1-15C alkyl, 2-15C alkenyl, halo-(1-15C alkyl), 3-6C cycloalkyl, halo-(3-6C cycloalkyl), heterocyclyl, heterocyclyl-(1-15C alkyl), aryl, aryl(1-15C alkyl), heteroaryl, heteroaryl-(1-15C alkyl) or alkoxy-(1-15C alkyl) (all optionally substituted by 1-15C alkyl, halo-(1-15C alkyl), 3-6C cycloalkyl, halo-(3-6C cycloalkyl), heterocyclyl, heterocyclyl-(1-15C alkyl), aryl, aryl-(1-15C alkyl), heteroaryl, 1-15C alkoxy, 1-15C alkylthio, OH, NO2, azido, acyloxy, carboxy or ester);R3R4, R5R6 = 5-7 membered heterocyclyl ring (optionally substituted by 1-15C alkyl, halo(1-15C alkyl), 3-6C cycloalkyl, halo(3-6C cycloalkyl), heterocyclyl, heterocyclyl-(1-15C alkyl), aryl, aryl-(1-15C alkyl), heteroaryl, 1-15C alkoxy, 1-15C alkylthio, OH, NO2, azido, acyloxy, carboxy or ester); andW1 = O or direct bond.Preferred Method: The method of preparing the laminate material, further comprises: applying the polymerization activator to the first or second substrate; providing the polymerization activator in the form of a base, base precursor, base creator or base enhancer within the polymerizable composition or on one of the substrates; providing the formulation additive. In the method of preparing the composite article, the step of molding the polymerizable composition is performed under temperature conditions less than 100 degrees C or at ambient temperature. The method of preparing the composite article, further comprises adding the formulation additive. EXAMPLE - 11.39 g of Multifunctional blend (comprised of 85 wt.% of diethyl methylene malonate, 10 wt.% of diethyl methylene malonate /1,6-hexanediol product and 5 wt.% of other (including diethyl malonate)) and 0.608 g of 10000 ppm methanesulfonic acid in diethyl methylene malonate stock solution were combined in a 100 ml polypropylene tripour, mixed with an overhead mechanical stirrer equipped with a 1'' dispersion blade at 250 revolutions per minute. Then, 18.012 g of alumina powder was slowly added over 10 minutes, increasing the stir rate as viscosity began to build. After 28 minutes of mixing at a shear rate of 2500 revolutions per minute, the solution began to exotherm slightly and the mixture was transferred to an aluminum weigh pan to cure.