NOVELTY - A barrier laminate (10) has an inorganic layer (1) and organic layer (b1) (2) on surface of inorganic layer (1). The organic layer (b1) contains polymer which is obtained by polymerizing polymeric composition containing polyfunctional (meth)acrylate, silicon compound (I), carboxylic-acid compound (II), and aromatic carboxylic-acid compound (III).    USE - Barrier laminate is used for gas-barrier film for device e.g. organic electroluminescent element, solar cell element (all claimed), liquid crystal display element and packaging material for foodstuffs, industrial products and pharmaceuticals.    ADVANTAGE - The barrier laminate has excellent adhesiveness, barrier performance, surface smoothness and heat resistance, and reduced generation of appearance gas.    DETAILED DESCRIPTION - A barrier laminate has an inorganic layer (1) and organic layer (b1) on surface of inorganic layer (1). The organic layer (b1) contains polymer which is obtained by polymerizing polymeric composition containing polyfunctional (meth)acrylate, silicon compound of formula: R1-Si(-R2)(-R3)-NH-Si(-R4)(-R5)-R6 (I), carboxylic-acid compound of formula: CH2-C(-R11)-A-R12-(COOH)n1 (II), and aromatic carboxylic-acid compound of formula (III).    R1-R6=alkyl or aryl (both optionally substituted), in which at least one is substituent having radically-polymerizable carbon-carbon double bond;    R11,R21=H or methyl;    R12=-CR2-, -O-, -CO-, -CR=CR-, arylene, heteroarylene, or bivalent coupling group;    A=-O- or -NR-;    R=H or substituent;    or two of R=ring;    R22=single bond, alkylene or arylene (both optionally substituted), structure in which two or more alkylene or arylene groups are connected by amide bond or ester bond, or coupling group which does not have aliphatic cyclic structure;and    n2=1-5.    The number of atoms in R22 is 2-82. INDEPENDENT CLAIMS are included for the following:    (1) gas barrier film;    (2) device; and    (3) manufacture of gas-barrier film.    DESCRIPTION OF DRAWING(S) - The drawing shows schematic cross-sectional view of barrier laminate.    Inorganic layers (1,3)    Organic layer (2)    Barrier laminate (10)