NOVELTY - A polynary organic/inorganic hybrid solar battery comprises a glass substrate, indium tin oxide layer as anode, zinc oxide-cadmium sulfide-antimony sulfide three component nano-rod array, lithium bis(trifluoromethane sulfonyl) imide-poly(2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene) (LiTFSI-MEH-PPV) layer, PEDOT: PSS as a hole transport layer and Au film layer, where the ITO layer is coated on a glass substrate as the anode of the battery group to the vertical growth in the ITO layer on top of three component nanorod array of electron transport ducts battery.    USE - Polynary organic/inorganic hybrid solar battery for use in photovoltaic material and low solar cell device.    ADVANTAGE - The battery can be prepared in simple and easy manner.    DETAILED DESCRIPTION - A polynary organic/inorganic hybrid solar battery comprises a glass substrate, indium tin oxide (ITO) layer as anode, zinc oxide (ZnO)-cadmium sulfide (CdS)-antimony sulfide (Sb2S3) three component nano-rod array, lithium bis(trifluoromethane sulfonyl) imide-poly(2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene) (LiTFSI-MEH-PPV) layer, PEDOT: PSS as a hole transport layer and Au film layer, where the ITO layer is coated on a glass substrate as the anode of the battery group to the vertical growth in the ITO layer on top of ZnO-CdS-Sb2S3 three component nanorod array of electron transport ducts battery with LiTFSI-MEH-PPV as the main light-absorbing material, and CdS and Sb2S3 auxiliary light absorbing material, LiTFSI-MEH-PPV filled ZnO-CdS- Sb2S3 gap of three components of the nanorods while at the top ZnOCdS-Sb2S3 nanorod arrays to form a three-component LiTFSI-MEHPPV film on LiTFSI-MEH-PPV film deposition PED0T: PSS as the hole transport layer, where hole transport layer is deposited on the Au film as the cathode of the cell, the ZnO-CdS- Sb2S3nanorods have three-component shell of Sb2S3 CdS intermediate shell, ZnO nanorods, the outer shell coated with CdS Sb2S3 intermediate shell, and the LiTFSI-MEH-PPV layer is doped by MEH-PPV LiTFSI composition. An INDEPENDENT CLAIM is also included for a method for preparing polynary organic/inorganic hybrid solar battery.