TECHNOLOGY FOCUS - POLYMERS - Preferred Components: The liquid crystal polymer article component is in the form of at least one selected from a molded article, a tube, a fiber, a billet, a sheet, and its hybrid. The adhesive comprises ethylene vinyl acetate copolymer. The liquid crystal polymer comprises at least one monomeric unit selected from a monomer according to Formula I, a monomer according to Formula II, a monomer according to Formula III, a monomer according to Formula IV, a monomer according to Formula V, a monomer according to Formula VI, a monomer accordi1g to Formula VII, and its combination.X'=selected from NR', CO, O, and its combination; andR and R'=independently selected from H, alkyl groups having 1 to 4 carbon atoms, fluoroalkyl groups having 1 to 4 carbon atoms, phenyl, and its combination.Adhesion enhancement compound is at least one selected from 2,6-naphthalene dicarboxylic acid, 6-hydroxyl naphthalene 2-carboxylic acid, p-hydroxybenzoic acid, terephthalic acid, isophthalic acid, benzenediol, a bisphenol, 4-aminophenol, acetaminophen, styrene, alpha -methyl styrene, halogenated styrene, acrylonitrile, methylacrylonitrile, acrylamide, methacrylamide, vinyl naphthalene, N-methylol acrylamide, vinyl acetate, vinylchloride, vinylidene chloride, benzyl acrylate, methacrylic acid, itaconic acid, fumaric acid, maleic acid, a compound according to Formula VIII, a compound according to Formula IX, a compound according to Formula X, a compound according to Formula X, a compound according to Formula XII, a compound according to Formula XIII, a compound according to Formula XIV, a compound according to Formula XV, and its combination.X=selected from NY'R', COOH, OH, and its combination;Y1 and Y'=independently selected from H, HOCH3, and its combination; andR and R'=independently selected from H, alkyl groups having 1 to 4 carbon atoms, fluoroalkyl groups having 1 to 4 carbon atoms, phenyl, and its combination.The liquid crystal polymer composition further comprises at least one selected from a reinforcing agent, a thermoplastic resin, a mold release-improving agent, a nucleating agent, an antioxidant, a stabilizer, a plasticizer, a slipping agent, a color protection agent, a coloring agent, an ultraviolet light absorber, an antistatic agent, a lubricant, a flame retardant, and its combination. The article further comprises a second layer such that the adhesive layer is disposed between the liquid crystal polymer article component and the second layer, the second layer comprising at least one selected from a substrate, an encapsulant layer, a peelable layer, an optoelectronic layer, a photovoltaic layer, a thermoplastic layer, and its combination. The layered article further comprises a photovoltaic layer and a second encapsulant layer, where the photovoltaic layer is disposed between the encapsulant layer and the second encapsulant layer. The liquid crystal polymer layer is at least one form selected from a molded article, a sheet, a tube, and a fiber. A second layer comprises at least one selected from a substrate, an adhesive layer, an encapsulant layer, a peelable layer, an optoelectronic layer, a photovoltaic layer, a thermoplastic layer, a second liquid crystal polymer layer, and its combination. The thermoplastic layer is polyurethane. Preferred Parameters: The liquid crystal polymer has an intrinsic viscosity ranging from about 0.1 dl/g to about 10 dl/g. The liquid crystal polymer composition has a water vapor transmission rate of about 3 g/m2/day or less, as measured by ASTM R1249-06 with a 25 micron thick sample of the liquid crystal polymer composition. It has an oxygen permeability of about 3 g/m2/day or less, as measured by ASTM D3985 with a 25 micron thick sample of the liquid crystal polymer composition. The liquid crystal polymer article component is a liquid crystal polymer layer with a thickness of about 10 microns to about 1500 microns. Liquid crystal polymer article component is adhered to the second layer with lap strength of about 1 MPa or greater. Liquid crystal polymer layer has water vapor permeability of less than about 1.0 g/m2-24 hours. Liquid crystal polymer layer has an oxygen permeability of about 3 g/m2/day or less, as measured by ASTM D3985 with a 25 micron thick sample of the liquid crystal polymer composition. Liquid crystal polymer layer has a thickness of about 1 micron to about 1500 microns. Preferred Composition: The adhesion enhancement compound is present in an amount ranging from about 0.01% to about 30% by weight of liquid crystal polymer. The high-temperature monomer is present in the liquid crystal polymer layer at a concentration of about 0.01% to about 30% by weight of the liquid crystal polymer layer. Preferred Product: The product is at least one selected from packaging, food packaging, beverage packaging, medical packaging, blister packs, chemical packaging, electronics packaging, electronics or its component, a circuit board, a flexible circuit board, a socket, a bobbin, a switch, a connector, a chip carrier, a sensor, a bio-container, a blood bag, a dialysis bag, a saline bag, a syringe, a vial, medical tubing, a urinary catheter, a cardiac catheter, an intravenous catheter, a feeding tube, a dialysis tubing, surgical equipment, a medical implant, a joint replacement, radiofrequency identification (RFID) tag, a pace maker, an implantable sensor, a channeled device, a channeled drug delivery device, an electrophoretic device, a fuel cell, a solar cell, a safety garment, and heat resistant belts. Preferred Process: The method further involves applying an optoelectronic to the adhesive; or applying a thermoplastic polymer to the adhesive. It also involves producing a product comprising the liquid crystal polymer layer having the adhesive layer disposed to it, where the product is one selected from packaging, food packaging, beverage packaging, medical packaging, a blister pack, chemical packaging, electronics packaging, an electronic component, a circuit board, a flexible circuit board, a bag for biological fluids, a blood bag, a dialysis bag, a saline bag, a medical device, a catheter, a piece of surgical equipment, a component of a piece of surgical equipment, a medical implant, a joint replacement, a fuel cell, a solar cell, a safety garment, a heat resistant belt, and its hybrid. The method further involves laminating the liquid crystal polymer layer having adhesive disposed to it with at least one layer selected from a substrate, an adhesive layer, an encapsulant layer, a peelable layer, an optoelectronic layer, a photovoltaic layer, a thermoplastic layer, a second liquid crystal polymer layer, and its combination. Preferred Device: The optoelectronic structure further comprises an encapsulant layer disposed on the optoelectronic device; a second adhesive layer disposed on the encapsulant layer; and a second liquid crystal polymer disposed on the second adhesive layer, the second liquid crystal polymer layer comprising a second liquid crystal polymer and a second high-temperature monomer. EXAMPLE - No suitable example given.