TECHNOLOGY FOCUS - INORGANIC CHEMISTRY - The method further involves combusting at least a portion of the H2-containing gas stream to produce electricity, the combusting optionally is done in a combustion zone of a second turbine, and the cathode inlet stream optionally comprises at least a portion of a combustion turbine exhaust generated by combustion of a carbon-containing fuel. The method further involves reacting at least a portion of the syngas-containing stream in the presence of a methanol synthesis catalyst under effective conditions for forming methanol to produce at least one methanol-containing stream and at least one stream comprising gaseous or liquid products, and optionally recycling at least a portion of the streams comprising gaseous or liquid products to form at least a portion of the cathode inlet stream. The method further involves optionally sending at least one CO2-containing stream derived from at least one first refinery process to the cathode inlet, separating CO2 from at least a portion of the anode exhaust to form a CO2-rich gas stream having a CO2 content greater than a CO2 content of the anode exhaust, and a CO2-depleted gas stream having a CO2 content less than the CO2 content of the anode exhaust, and delivering the CO2-depleted gas stream to at least one second refinery process. The method further involves separating CO2 from at least a portion of the anode exhaust to produce a CO2-rich stream having a CO2 content greater than a CO2 content of the anode exhaust and a CO2-depleted gas stream having an H2 content greater than an H2 content of the anode exhaust, and using at least a portion of the CO2-depleted gas stream in an ammonia synthesis process, in a process for synthesis of an organic nitrogen-containing compound, or in both. The method further involves withdrawing, from an anode exhaust, a first gas stream comprising CO, the anode exhaust having a pressure of less than or equal to 500 kPag, introducing the first gas stream withdrawn from the anode exhaust into a process for production of iron and/or steel, and optionally withdrawing a second gas stream comprising H2 from the anode exhaust and, if withdrawn, using the second gas stream as fuel for heating in the process for production of iron and/or steel. The method further involves generating an anode exhaust comprising H2, CO, H2O, and at least 20 vol.% CO2, reacting at least a portion of the anode exhaust under effective Fischer-Tropsch conditions in the presence of a shifting Fischer-Tropsch catalyst to produce at least one gaseous product and at least one non-gaseous product, where a CO2 concentration in at least a portion of the anode exhaust is at least 80% of a CO2 concentration in the anode exhaust, and recycling at least a portion of the gaseous product to the cathode inlet. The method further involves generating an anode exhaust comprising H2, CO, CO2, and H2O, and having a ratio of H2 to CO of at least 2.5:1, reducing the ratio of H2 to CO in at least a portion of the anode exhaust to a ratio of 1.7:1 to 2.3:1 to form a classic syngas stream, which also has a CO2 concentration that is at least 60% of a CO2 concentration in the anode exhaust, reacting the classic syngas stream under effective Fischer-Tropsch conditions in the presence of a non-shifting Fischer-Tropsch catalyst to produce at least one gaseous product and at least one non-gaseous product, and optionally recycling at least a portion of the gaseous product to the cathode inlet. The method further involves generating an anode exhaust comprising H2, CO, and CO2, having a ratio of H2 to CO of at least 2.5:1, and having a CO2 content of at least 20 vol.%, removing water and CO2 from at least a portion of the anode exhaust to produce an anode effluent gas stream, the anode effluent gas stream having a concentration of water that is less than half of a concentration of water in the anode exhaust, having a concentration of CO2 that is less than half of a concentration of CO2 in the anode exhaust, the anode effluent gas stream also having a ratio of H2 to CO of less than or equal to 2.3:1, and reacting at least a portion of the anode effluent gas stream over a non-shifting Fischer-Tropsch catalyst to produce at least one gaseous product and at least one non-gaseous product.