TECHNOLOGY FOCUS - ELECTRICAL POWER AND ENERGY - Preferred System: The system connected to an electrical grid configured to provide renewables integration, peak load shifting, grid firming, baseload power generation/consumption, energy arbitrage, transmission and distribution asset deferral, weak grid support, and/or frequency regulation. The system configured to provide stable power for remote camps, forward operating bases, off-grid telecommunications, or remote sensors.    TECHNOLOGY FOCUS - INORGANIC CHEMISTRY - Preferred Components: The first and/or second metal-ligand coordination compound comprises Al, Ca, Ce, Co, Cr, Fe, Mg, Mn, Mo, Si, Sn, Ti, W, Zn, or Zr, preferably Cr, Ti, or Fe; or Al3+, Ca2+, Ce4+, Co3+, Cr3+, Fe3+, Mg2+, Mn3+, Mo6+, Si4+, Sn4+, Ti4+, W6+, Zn2+, or Zr4+.    TECHNOLOGY FOCUS - ORGANIC CHEMISTRY - Preferred Components: The metal ligand coordination compound is of formula M(L1)x(L2)y(L3)z(m). The first aqueous electrolyte comprises a first metal-ligand coordination compound and the second aqueous electrolyte comprises a second metal-ligand coordination compound, where the first and second metal-ligand coordination compounds are different. The first and/or second metal-ligand coordination compound comprises at least one ligand (I). The redox-active metal ligand coordination compound comprises at least one ligand f formula (Ia), (Ib) or (Ic). The first and second metal-ligand coordination compound comprises at least one ascorbate, a catecholate, citrate, a glycolate or polyol, gluconate, glycinate, alpha-hydroxyalkanoate, beta-hydroxyalkanoate, gamma-hydroxyalkanoate, malate, maleate, phthalate, sarcosinate, salicylate, or lactate ligand. The second metal-ligand coordination compound comprises an iron hexacyanide compound. The first and/or second metal-ligand coordination compounds having a hydrodynamic diameter; and the separator has a mean pore size, where the hydrodynamic diameter of the coordination compound is larger than the mean pore size of the separator. The first and second metal-ligand coordination compounds each exhibits reversible electrochemical kinetics. The second metal-ligand coordination compound comprises at least one catechol or pyrogallol ligand. The second metal-ligand coordination compound is an iron hexacyanide compound.M=non-zero valent metal or metalloid of groups 2-16, including lanthanides and actinides;x, y, and z=0, 1, 2, or 3;x+y+z=1-3;m=-5, -4, -3, -2, -1, 0, 1, 2, 3, 4, or 5;L1, L2, and L3=ascorbate, citrate, a glycolate, gluconate, glycinate, alpha-hydroxyalkanoate, beta-hydroxyalkanoate, gamma-hydroxyalkanoate, malate, maleate, phthalate, a polyol, sarcosinate, salicylate, lactate, or a compound of formula (I) or its oxidized or reduced form;Ar'=5-20 membered aromatic moiety, optionally comprising O, N, or S heteroatoms;X1 and X2=-OH, -NHR', -SH, or its anion (where X1 and X2 are positioned ortho to one another);R1=H, 1-6C alkoxy, 1-6C alkyl, 1-6C alkenyl, 1-6C alkynyl, 5-6 membered aryl or heteroaryl, a boric acid or its salt, carboxy acid or its salt, 2-6C carboxylate, cyano, halo, hydroxyl, nitro, sulfonate, sulfonic acid or its salt, phosphonate, phosphonic acid or its salt, or a polyglycol;R'=H or 1-3C alkyl;n=0-10.