TECHNOLOGY FOCUS - ORGANIC CHEMISTRY - Preparation (claimed): The amine compound (I) is prepared by reacting compound (IA) and amine compound of formula: Ar1-NH-Ar2 or Ar1-NH2 in presence of a palladium compound, a trialkyl phosphine compound and a base. Preferred Compound: The amine compound (I) is preferably of formula (II). Preferred Definitions:    Ar1,Ar2=phenyl, 4-methylphenyl, 3-methylphenyl, 1-naphthyl, 2-naphthyl, 4-biphenylyl, p-terphenyl or 4-(9-carbazolyl)phenyl;    R1,R2=H, methyl, ethyl, phenyl, tolyl, or methoxyphenyl;and    R3,R4=H, phenyl, tolyl, methyl, methoxy, diphenylamino, phenyltolylamino, or ditolylamino.    SPECIFIC COMPOUNDS - 84 Amine compounds are disclosed e.g. N-(4-(9H-carbazol-9-yl)phenyl)-10,10-dimethyl-N-phenyl-8-thiatetracyclo(7.7.0.02,7.011,16)hexadeca-1(9),2(7),3,5,11(16),12,14-heptaen-13-amine of formula (IA), 10,10-dimethyl-N,N-diphenyl-8-thiatetracyclo(7.7.0.02,7.011,16)hexadeca-1(9),2(7),3,5,11(16),12,14-heptaen-13-amine, 10,10-dimethyl-N,N-bis(4-phenylphenyl)-8-thiatetracyclo(7.7.0.02,7.011,16)hexadeca-1(9),2(7),3,5,11(16),12,14-heptaen-13-amine, 10,10-dimethyl-N,N-diphenyl-8-oxatetracyclo(7.7.0.02,7.011,16)hexadeca-1(9),2(7),3,5,11(16),12,14-heptaen-13-amine and 10,10-dimethyl-N-(naphthalen-1-yl)-N-phenyl-8-oxatetracyclo(7.7.0.02,7.011,16)hexadeca-1(9),2(7),3,5,11(16),12,14-heptaen-13-amine.    EXAMPLE - 729.1 mg 13-Chloro-10,10-dimethyl-8-thiatetracyclo(7.7.0.02,7.011,16)hexadeca-1(9),2(7),3,5,11(16),12,14-heptaene, 899.6 mg N-phenyl-N-4-(9-carbazolyl)phenylamine, 344 mg sodium tertbutoxide, 12 mg palladium acetate, 41 mg tri-tert-butylphosphine and 6 mL o-xylene were stirred at 140 degrees C for 15 hours. 10 mL Water was added after completion of reaction, stirred for 30 minutes, aged at room temperature and the aqueous layer was separated-removed. The organic layer was dried with magnesium sulfate, concentrated, and purified using silica-gel column chromatography, to obtain N-(4-(9H-carbazol-9-yl)phenyl)-10,10-dimethyl-N-phenyl-8-thiatetracyclo(7.7.0.02,7.011,16)hexadeca-1(9),2(7),3,5,11(16),12,14-heptaen-13-amine with yield of 84% and purity of 99.9%.